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• W2031644164 endingPage "420" @default.
• W2031644164 startingPage "415" @default.
• W2031644164 abstract "Cationic transition metal complexes of 2,6-lutidine N-oxide (2,6-LNO) were synthesized and studied. For the monomeric tetra-cordinated cations of the type [M(2,6-LNO)4]2+ (M = Fe, Co, Ni, Cu, Zn), stabilization of an essentially planar configuration is interpreted in terms of a combination of steric and electronic effects. The MO4 grouping in the high-spin CuII and the low-spin NiII complex is assigned a D4h symmetry. Evidence is presented in favor of a monomeric structure, with essentially planar MO4 groupings for the high-spin CoII and the partially spin-paired FeII complex. Coordination of one monodentate OClO3 group in [Mn(2,6-LNO)4(OClO3)]+ is attributed to the anticipated instability of a planar configuration for the MnII ion. CrIII forms a hexacoordinated cationic complex. Finally, the formation of tetracoordinated NiII complexes with pyridine N-oxide and its monosubstituted derivatives is favored in triethyl orthoformate solution." @default.
• W2031644164 created "2016-06-24" @default.
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• W2031644164 date "1969-01-01" @default.
• W2031644164 modified "2023-09-23" @default.
• W2031644164 title "Spin-free and spin-paired transition metal perchlorate complexes of 2,6-lutidine N-oxide" @default.
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• W2031644164 doi "https://doi.org/10.1016/s0020-1693(00)92523-4" @default.
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