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- W2031652069 abstract "Abstract A method for the gram‐scale preparation of functionalized 4,4′‐bisquinolones using a microwave‐assisted Ullmann‐type homocoupling reaction is described. The method is catalytic in nickel(0) which is generated in situ by reduction from an inexpensive nickel(II) source and utilizes readily available 4‐chloroquinolin‐2(1 H )‐ones as starting materials. In contrast to the alternative palladium(0)‐catalyzed one‐pot borylation/Suzuki cross‐coupling reaction, the new method avoids the use of an expensive catalyst and cross‐coupling partner such as bis(pinacolato)diboron." @default.
- W2031652069 created "2016-06-24" @default.
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- W2031652069 date "2007-10-08" @default.
- W2031652069 modified "2023-09-30" @default.
- W2031652069 title "Synthesis of Symmetrical Bisquinolones <i>via</i> Nickel(0)‐Catalyzed Homocoupling of 4‐Chloroquinolones" @default.
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- W2031652069 doi "https://doi.org/10.1002/adsc.200700081" @default.
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