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• W2031657982 abstract "The microwave induced plasmas have been successfully used as an excitation source in atomic emission and mass spectrometry for the analytical determination of substances. In this work a study of the influence of the thermodynamic equilibrium state over the capacity of sample excitation of an argon plasma flame sustained by a surface wave at atmospheric pressure is presented. The state of the thermodynamic equilibrium in the discharge is determined by the relation between its temperatures and densities. The values of these parameters depend on the energy available in the discharge, which is also responsible for the excitation of the samples introduced into the plasma. We have compared the behavior of two characteristic parameters of plasma (electron density and temperature) and of the ArI level population with the microwave power. The results have shown that the values of these parameters and populations had a tendency to remain constant for microwave powers above a certain value. Thus, from 100 W only a part of the energy injected into the discharge is absorbed in the plasma and the plasma equilibrium state is not consequently modified. This behavior is the same as that found for atomic lines of both halogens and iron introduced as samples into the plasma and seems to show that if the plasma is close to thermodynamic equilibrium the excitation of the samples is favored." @default.
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• W2031657982 date "2002-08-16" @default.
• W2031657982 modified "2023-09-27" @default.
• W2031657982 title "Influence of the thermodynamic equilibrium state in the excitation of samples by a plasma at atmospheric pressure" @default.
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• W2031657982 doi "https://doi.org/10.1063/1.1492869" @default.
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