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- W2031673544 abstract "Abstract The homo‐ and heterobimetallic complexes [Cp*Ru(μ‐Cl) 3 ML] [LM = (C 6 H 6 )Ru, (cymene)Ru, (1,3,5‐C 6 H 3 i Pr 3 )Ru, Cp*Rh, Cp*Ir] were prepared by reaction of [Cp*Ru(μ‐OMe)] 2 with Me 3 SiCl and subsequent addition of [LMCl 2 ] 2 .The complexes [Cp*Ru(μ‐Cl) 3 Ru(cymene)] and [Cp*Ru(μ‐Cl) 3 IrCp*] were characterized by single‐crystal X‐ray analyses. In crossover experiments with [Cp*Rh(μ‐Cl) 3 RuCl(PPh 3 ) 2 ] and [Cp*Ru(μ‐Cl) 3 Ru(1,3,5‐C 6 H 3 i Pr 3 )] in CD 2 Cl 2 , a dynamic equilibrium with the complexes [Cp*Rh(μ‐Cl) 3 RuCp*] and [(1,3,5‐C 6 H 3 i Pr 3 )Ru(μ‐Cl) 3 RuCl(PPh 3 ) 2 ] was rapidly established, demonstrating the kinetic lability of the triple chloro bridge. Upon reaction of [Cp*Rh(μ‐Cl) 3 RuCp*] with benzene, the ionic complex [Cp*Ru(C 6 H 6 )][Cp*RhCl 3 ] was formed, which was characterized by X‐ray crystallography. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
- W2031673544 created "2016-06-24" @default.
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- W2031673544 date "2005-12-22" @default.
- W2031673544 modified "2023-10-17" @default.
- W2031673544 title "Synthesis, Structure and Reactivity of Homo‐ and Heterobimetallic Complexes of the General Formula [Cp*Ru(μ‐Cl)<sub>3</sub>ML] [LM = (arene)Ru, Cp*Rh, Cp*Ir]" @default.
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- W2031673544 doi "https://doi.org/10.1002/ejic.200500692" @default.
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