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- W2031748414 abstract "The NAD+ subunit 1-methyl-3-carbamoyl pyridinium cation (or 1-methyl nicotinamide cation, MNA+) forms an ion pair with [Fe(CN)6]4− which shows a new absorption (λmax=392 nm) in the electronic spectrum. This band is assigned to an outer-sphere charge transfer (OSCT) transition from [Fe(CN)6]4− to MNA+. In aqueous solution OSCT excitation leads to a photoredox reaction with the formation of [Fe(CN)6]3− and the radical MNA which undergoes a dimerization or, more likely, a further reduction to MNAH." @default.
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- W2031748414 date "2000-04-01" @default.
- W2031748414 modified "2023-09-26" @default.
- W2031748414 title "Photochemical reduction of 1-methyl-3-carbamoyl-pyridinium by hexacyanoferrate(II) induced by outer-sphere charge transfer excitation" @default.
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- W2031748414 doi "https://doi.org/10.1016/s0020-1693(99)00481-8" @default.
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