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• W2031772817 startingPage "A729" @default.
• W2031772817 abstract "The work of Blatt and Kropschot was extended to dilute CuAg and CuAu alloys; simultaneous measurements of the thermopower and thermal conductivity were made on CuSn alloys. The decomposition of the absolute thermopower of copper into diffusion ${S}_{d}$ and phonon drag ${S}_{g}$ contributions proposed by Blatt and Kropschot was verified. It is based on the observed quenching of ${S}_{g}$ by large-mass solutes due to anisobaric phonon scattering. It was found that ${S}_{g}$ is completely suppressed by approximately 1 at.% of Ag or Sn and by 0.4 at.% of Au. In the temperature region ($Tensuremath{simeq}60ifmmode^circelsetextdegreefi{}$K) where anisobaric scattering is important in limiting the lattice conduction ${ensuremath{kappa}}_{g}$, it was observed that ${ensuremath{kappa}}_{g}$ is reduced considerably less than ${S}_{g}$. It is suggested that this is due to the characteristic dispersion of phonons of large wave vector. At low temperatures, where the Debye model holds, comparison of ${S}_{g}$ and ${S}_{d}$ with specific-heat data leads to the conclusion that the umklapp contribution ${{S}_{g}}^{U}$ is 25% larger in magnitude than the normal contribution ${{S}_{g}}^{N}$. This is in agreement with estimates by Ziman of the relative importance of normal and umklapp processes in copper." @default.
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• W2031772817 date "1964-11-02" @default.
• W2031772817 modified "2023-09-25" @default.
• W2031772817 title "Thermoelectric Power of Dilute Copper Alloys. II" @default.
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• W2031772817 doi "https://doi.org/10.1103/physrev.136.a729" @default.
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