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- W2031775210 abstract "Representative vinylcyclopropanes (IaIc) were hydrated in a Markovnikov fashion by oxymercuration-demercuration. Isolated yields of α-cyclopropyl-substituted alcohols were more than 80%. 2,2-Diphenyl-l-vinylcyclopropane (Id) was the only olefin that produced a mixture of the expected alcohol, IId, and a rearranged product III. At 0° C, However, the amount of III was minimal (ca. 6%), and hence the Markovnikov hydration of Id was accomplished. The consumption of two molar equivalents of mercuric acetate in the formation of III was demonstrated by demercuration with sodium borodeuteride." @default.
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- W2031775210 date "1978-08-01" @default.
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- W2031775210 title "Markovnikov hydration of vinylcyclopropanes by oxymercuration-demercuration." @default.
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