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- W2031819170 abstract "The nonanuclear cluster complexes [Ru9(μ-H)2(μ4-κ2-ampy)4(CO)17] and [Ru9(μ3-H)(μ-H)(μ4-κ2-ampy)3(CO)18] (ampy = 2-imido-6-methylpyridine) have been prepared by heating [Ru6(μ3-H)2(μ5-κ2-ampy)(μ-CO)2(CO)14] in undecane at reflux temperature. Both compounds feature a novel metallic skeleton that can be described as a pentagonal bipyramid with two equatorial edges spanned by metal atoms. In both cases, the ampy ligands are attached to edge-bridging Ru atoms through the pyridine N atoms, while their imido N atoms cap metallic triangles formed by the metal atoms of one of the metal-bridged edges and one of the apical metal atoms." @default.
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- W2031819170 date "2006-10-13" @default.
- W2031819170 modified "2023-10-17" @default.
- W2031819170 title "Nonanuclear Ruthenium Carbonyl Cluster Complexes with a Novel Metallic Skeleton: Pentagonal Bipyramid with Two Equatorial Edges Spanned by Metal Atoms" @default.
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- W2031819170 doi "https://doi.org/10.1021/om060655u" @default.
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