FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2031827720> ?p ?o ?g. }

• W2031827720 endingPage "395" @default.
• W2031827720 startingPage "395" @default.
• W2031827720 abstract "The recombination reaction between Fe and O2 has been studied by the pulsed photodissociation at 193.3 nm of ferrocene vapour to produce Fe atoms in an excess of O2 and N2 bath gas, followed by time-resolved laser-induced fluorescence spectroscopy of atomic Fe at 248.3 nm [Fe(x5F°5–a 5D4)]. This yields k(288 < T/K < 592)=(4.34 ± 0.96)× 10–30 exp[–(16.94 ± 0.67) kJ mol–1/RT] cm6 molecule–2 s–1, where the quoted uncertainty is 2σ. Ab initio quantum calculations on FeO2 indicate that the ground electronic state is a superoxide with an isosceles triangular geometry, FeO2(7A1). The bond energy, Do(Fe—O2), is estimated to be 180 ± 50 kJ mol–1. These calculations, combined with RRKM theory, demonstrate that the positive temperature dependence of this recombination reaction is caused by barriers in the entrance channels of the manifold of potential-energy surfaces that arise from the interaction of Fe(a 5Di) and O2(3Σ–g). The recommended rate coefficient between 150 and 2000 K is given by log(k/cm6 molecule–2 s–1)=– 161.87 + 119.32x– 36.057x2+ 3.6303x3, where x= log(T), and the uncertainty in k is estimated to be ±25%. The implications of this result for the chemistry of meteor-ablated Fe in the upper atmosphere are then considered." @default.
• W2031827720 created "2016-06-24" @default.
• W2031827720 creator A5011868329 @default.
• W2031827720 creator A5037222986 @default.
• W2031827720 date "1994-01-01" @default.
• W2031827720 modified "2023-09-23" @default.
• W2031827720 title "Experimental and theoretical study of the reaction Fe + O2+ N2? FeO2+ N2" @default.
• W2031827720 cites W1565195035 @default.
• W2031827720 cites W1675674910 @default.
• W2031827720 cites W1964501305 @default.
• W2031827720 cites W1970001220 @default.
• W2031827720 cites W1973855356 @default.
• W2031827720 cites W1975423769 @default.
• W2031827720 cites W1983480158 @default.
• W2031827720 cites W1984236022 @default.
• W2031827720 cites W1984333422 @default.
• W2031827720 cites W1990833835 @default.
• W2031827720 cites W2003699352 @default.
• W2031827720 cites W2009387482 @default.
• W2031827720 cites W2009960177 @default.
• W2031827720 cites W2015662475 @default.
• W2031827720 cites W2033276544 @default.
• W2031827720 cites W2043061827 @default.
• W2031827720 cites W2044426006 @default.
• W2031827720 cites W2045233973 @default.
• W2031827720 cites W2052367979 @default.
• W2031827720 cites W2068995207 @default.
• W2031827720 cites W2075769392 @default.
• W2031827720 cites W2078372791 @default.
• W2031827720 cites W2082420463 @default.
• W2031827720 cites W2083397857 @default.
• W2031827720 cites W2088647385 @default.
• W2031827720 cites W2096476082 @default.
• W2031827720 cites W2138219498 @default.
• W2031827720 cites W2157748918 @default.
• W2031827720 cites W2158338515 @default.
• W2031827720 cites W2165705195 @default.
• W2031827720 cites W2396646892 @default.
• W2031827720 cites W271247170 @default.
• W2031827720 cites W47509925 @default.
• W2031827720 doi "https://doi.org/10.1039/ft9949000395" @default.
• W2031827720 hasPublicationYear "1994" @default.
• W2031827720 type Work @default.
• W2031827720 sameAs 2031827720 @default.
• W2031827720 citedByCount "53" @default.
• W2031827720 countsByYear W20318277202012 @default.
• W2031827720 countsByYear W20318277202013 @default.
• W2031827720 countsByYear W20318277202016 @default.
• W2031827720 countsByYear W20318277202017 @default.
• W2031827720 countsByYear W20318277202018 @default.
• W2031827720 countsByYear W20318277202020 @default.
• W2031827720 crossrefType "journal-article" @default.
• W2031827720 hasAuthorship W2031827720A5011868329 @default.
• W2031827720 hasAuthorship W2031827720A5037222986 @default.
• W2031827720 hasConcept C113196181 @default.
• W2031827720 hasConcept C121332964 @default.
• W2031827720 hasConcept C147789679 @default.
• W2031827720 hasConcept C178790620 @default.
• W2031827720 hasConcept C183971685 @default.
• W2031827720 hasConcept C184779094 @default.
• W2031827720 hasConcept C185592680 @default.
• W2031827720 hasConcept C2781442258 @default.
• W2031827720 hasConcept C32891209 @default.
• W2031827720 hasConcept C32909587 @default.
• W2031827720 hasConcept C43617362 @default.
• W2031827720 hasConcept C54582936 @default.
• W2031827720 hasConcept C62520636 @default.
• W2031827720 hasConcept C75473681 @default.
• W2031827720 hasConceptScore W2031827720C113196181 @default.
• W2031827720 hasConceptScore W2031827720C121332964 @default.
• W2031827720 hasConceptScore W2031827720C147789679 @default.
• W2031827720 hasConceptScore W2031827720C178790620 @default.
• W2031827720 hasConceptScore W2031827720C183971685 @default.
• W2031827720 hasConceptScore W2031827720C184779094 @default.
• W2031827720 hasConceptScore W2031827720C185592680 @default.
• W2031827720 hasConceptScore W2031827720C2781442258 @default.
• W2031827720 hasConceptScore W2031827720C32891209 @default.
• W2031827720 hasConceptScore W2031827720C32909587 @default.
• W2031827720 hasConceptScore W2031827720C43617362 @default.
• W2031827720 hasConceptScore W2031827720C54582936 @default.
• W2031827720 hasConceptScore W2031827720C62520636 @default.
• W2031827720 hasConceptScore W2031827720C75473681 @default.
• W2031827720 hasIssue "3" @default.
• W2031827720 hasLocation W20318277201 @default.
• W2031827720 hasOpenAccess W2031827720 @default.
• W2031827720 hasPrimaryLocation W20318277201 @default.
• W2031827720 hasRelatedWork W2005431797 @default.
• W2031827720 hasRelatedWork W2013822265 @default.
• W2031827720 hasRelatedWork W2022976216 @default.
• W2031827720 hasRelatedWork W2046944648 @default.
• W2031827720 hasRelatedWork W2054185339 @default.
• W2031827720 hasRelatedWork W2083597126 @default.
• W2031827720 hasRelatedWork W2094100290 @default.
• W2031827720 hasRelatedWork W2126527832 @default.
• W2031827720 hasRelatedWork W2178498111 @default.
• W2031827720 hasRelatedWork W2301892073 @default.
• W2031827720 hasVolume "90" @default.
• W2031827720 isParatext "false" @default.

• next