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• W2031856218 endingPage "4189" @default.
• W2031856218 startingPage "4186" @default.
• W2031856218 abstract "Polarized resonant x-ray fluorescence spectroscopy at O $1s$ resonances was used to study ${mathrm{CuGeO}}_{3}.$ Two distinct spectral contributions are identified, i.e., an intense ``main band'' of soft-x-ray fluorescence, reflecting primarily bandlike $mathrm{O} 2p$ states, and resonant inelastic x-ray scattering (RIXS) characterized by spectral features that disperse linearly with excitation energy and resonate at the $mathrm{O} 1s$ pre-edge peak. RIXS reflects excitoniclike (``optical'') final states and has previously only been observed for metal-ion core edges. Moreover, analysis of the excitation energy and polarization dependence of the main band allows the identification of features deriving from the site-specific partial density of states as well as strong evidence for the observation of a two-hole state (Zhang-Rice singlet)." @default.
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• W2031856218 date "2000-02-01" @default.
• W2031856218 modified "2023-10-16" @default.
• W2031856218 title "Bandlike and excitonic states of oxygen in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>CuGeO</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mo>:</mml:mo></mml:math>Observation using polarized resonant soft-x-ray emission spectroscopy" @default.
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• W2031856218 doi "https://doi.org/10.1103/physrevb.61.4186" @default.
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