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• W2031860317 endingPage "175402" @default.
• W2031860317 startingPage "175402" @default.
• W2031860317 abstract "Li4Ti5O12/rutile TiO2 (LTO-RT) composites with Li/Ti molar ratios of 3:5, 4:5 and 4.5:5 have been successfully synthesized with TiO2 microspheres as a precursor. Furthermore, C-coated LTO-RT mesoporous microspheres with a molar ratio of 4:5 (C/4-5-LTO-RT) have been prepared based on the LTO-RT composite through a hydrothermal method and high temperature calcination. After various characterizations, it is found that carbon plays a pivotal role in retaining the porous nanostructure of the original as-prepared TiO2 precursor in the overall process. Substantially, C/4-5-LTO-RT still shows a high specific surface area of 63.70 m2 g−1 even after high temperature treatment at 800 °C. Since the porous nanostructure offers open and direct channels for the diffusion of Li ions and electrons and carbon decoration also efficiently improves the electrical conductivity, the sample of C/4-5-LTO-RT shows an enhanced electrochemical performance. In addition, the presence of nanosized rutile TiO2 in C/4-5-LTO-RT has an important contribution to the high electrochemical performance, as does the fast lithium ion diffusion along the [001] direction." @default.
• W2031860317 created "2016-06-24" @default.
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• W2031860317 date "2014-04-10" @default.
• W2031860317 modified "2023-10-16" @default.
• W2031860317 title "Carbon-decorated Li₄Ti₅O₁₂/rutile TiO₂ mesoporous microspheres with nanostructures as high-performance anode materials in lithium-ion batteries" @default.
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• W2031860317 doi "https://doi.org/10.1088/0957-4484/25/17/175402" @default.
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