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• W2031865618 endingPage "652" @default.
• W2031865618 startingPage "647" @default.
• W2031865618 abstract "Single crystals of TlMo6O17 purple bronze have been grown using a temperature gradient flux technique. TlMo6O17 is trigonal with space group P3 or P3 and a = 5.543(2)Å, c = 14.000(2) and appears to be isostructural with K0.9Mo6O17. The transport properties of TlMo6O17 are similar to that of K0.9Mo6O17. The temperature dependence of the resistivity shows a metal-metal transition at ∼113K, probably associated with a charge-density-wave driven phase transition. The magnetic susceptibility decreases sharply near the temperature of the anomaly seen in the resistivity. The electronic properties of the quasi 2D purple bronzes, A0.9Mo6O17 with A = Li, Na, K, Tl are compared. It is shown that despite the similarity of the basic Mo6O17 network structure in all, the properties vary substantially with the A cations. In contrast, the quasi 1D blue bronzes, A0.3MoO3 with A = K, Rb, Tl have nearly identical transport properties." @default.
• W2031865618 created "2016-06-24" @default.
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• W2031865618 date "1986-09-01" @default.
• W2031865618 modified "2023-09-27" @default.
• W2031865618 title "Charge-density-wave instability in TlMo6O17, a new quasi-two-dimensional purple bronze" @default.
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• W2031865618 doi "https://doi.org/10.1016/0038-1098(86)90365-0" @default.
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