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- W2031873281 abstract "Treatment of Pd((S,S)-Chiraphos)(o-An)(I) (3, o-An = o-MeOC6H4) with either enantiomer of highly enantioenriched PH(Me)(Ph)(BH3) (1) gave the phosphido-borane complex Pd((S,S)-Chiraphos)(o-An)(P(Me)(Ph)(BH3)) (4) with retention of configuration at phosphorus, as shown by X-ray crystal structure determinations for both diastereomers of 4. Heating either diastereomer of 4 with diphenylacetylene gave Pd((S,S)-Chiraphos)(PhCCPh) (5) and P(o-An)(Me)(Ph)(BH3) (2) with retention of configuration at phosphorus." @default.
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- W2031873281 date "2003-01-11" @default.
- W2031873281 modified "2023-10-18" @default.
- W2031873281 title "Stereochemistry of Palladium-Mediated Synthesis of PAMP−BH<sub>3</sub>: Retention of Configuration at P in Formation of Pd−P and P−C Bonds" @default.
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- W2031873281 doi "https://doi.org/10.1021/ja029404c" @default.
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