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• W2031874013 abstract "The formation of diamond from CaCO3 was studied in a reduced C–O–H fluid mainly composed of CH4 and H2O under diamond-stable HP–HT conditions at 7.7 GPa and 1500 °C in order to examine the genesis of natural diamonds experimentally and to present a new synthesis process of diamond. As a result, CaCO3 was reacted with reduced C–O–H fluid very rapidly, and most of the starting CaCO3 was converted to Ca(OH)2 and C within 1 h. The elemental carbon thus formed was graphite although the experiments were carried out deep in the diamond-stable HP–HT region, but it was transformed to diamond after 12 h. Graphite and diamond had the morphology characteristics of solution growth: the former was flaky and a few μm in size, and the latter was octahedral with sharp edges and flat surfaces and a few tens of μm in size." @default.
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• W2031874013 date "2002-08-01" @default.
• W2031874013 modified "2023-09-26" @default.
• W2031874013 title "Formation of diamond from CaCO3 in a reduced C–O–H fluid at HP–HT" @default.
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• W2031874013 doi "https://doi.org/10.1016/s0925-9635(02)00053-5" @default.
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