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• W2031875660 abstract "The title complex, [SnIV(C44H28N4)(CNO)(OH)], exhibits substitutional disorder of the OH− and OCN− axial ligands. Thus, the cyanato-O ligand and the hydroxyl group bonded to the central SnIV atom share statistically the axial position. The SnIV ion is hexa­coordinated by the four N atoms of the pyrrole rings of the tetra­phenyl­porphyrin (TPP) and the O atoms of the two disordered OCN− and OH− axial ligands. The equatorial tin–pyrrole N atom distance (Sn—Np) is 2.100 (2) Å and the axial Sn—O(OCN) or Sn—O(OH) bond length is 2.074 (2) Å." @default.
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• W2031875660 date "2011-06-11" @default.
• W2031875660 modified "2023-10-17" @default.
• W2031875660 title "Substitutional disorder in bis[(cyanato-κ<i>O</i>)/hydroxido(0.5/0.5)](5,10,15,20-tetraphenylporphyrinato-κ⁴<i>N</i>)tin(IV)" @default.
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• W2031875660 doi "https://doi.org/10.1107/s1600536811021544" @default.
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