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- W2031879220 abstract "A dynamic mechanical study has been made of two series of partially hydrolyzed ethylene-vinyl acetate copolymers. Series A contains 75 mole % ethylene and series B contains 59 mole % ethylene. The frequencies employed were 3.5, 11, and 110 Hz, and the temperature range was from −180° to +120°C. Three relaxation regions are discernable in this range and these are labeled α, β, and γ in order of decreasing temperature. The α relaxation is associated with the glass transition of the copolymers. The β relaxation is absent in the unhydrolyzed copolymers and is dependent on hydroxyl content. It is assigned to local motions of hydrogen bonded groups. The γ relaxation is insensitive to hydroxyl content and is assigned to local motions of methylene sequences. The above assignments are supported by the effect of water added to the polymers. Added water decreases the temperatures of the α and β relaxations but does not affect the γ relaxation significantly. The magnitude of the β relaxation is considerably enhanced by water." @default.
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- W2031879220 date "1971-01-01" @default.
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- W2031879220 title "Dynamic mechanical behavior of partially hydrolyzed ethylene-vinyl acetate copolymers" @default.
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- W2031879220 doi "https://doi.org/10.1002/polc.5070350110" @default.
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