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- W2031925275 abstract "The syntheses of end-functional polyisobutylenes (PIBs) including hydroxy, amino, carboxy, azide, propargyl, methoxy, and thymine end groups have been accomplished using nucleophilic substitution reactions. SN2 reactions on PIB-Allyl-X (X = Cl or Br), the trans-1,4 addition product of the capping reaction of living PIB with 1,3-butadiene, with different nucleophiles successfully yielded the corresponding PIB-Allyl-OH, PIB-Allyl-OMe, PIB-Allyl-NH2, PIB-Allyl-OCH2C≡CH, PIB-Allyl-N3, and PIB-Allyl-CH2COOH with quantitative functionalization as determined by 1H and 13C NMR, FT-IR, and matrix-assisted time-of-flight mass spectroscopy. As expected, the rate of substitution was faster with PIB-Allyl-Br compared to PIB-Allyl-Cl. GPC analysis of the precursor PIB-Allyl-X and the products indicated that the polymer chain is unaffected by the substitution reactions. The synthesis of hydroxy telechelic PIBs was also achieved using X-Allyl-PIB-Allyl-X at reaction conditions similar to that employed for the preparation of PIB-Allyl-OH. The methodology was extended to the synthesis of PIB block copolymers by employing polymeric nucleophiles. PIB-b-poly(ethylene oxide) (PEO) was synthesized by the nucleophilic substitution of PIB-Allyl-Cl with PEO-O−Na+." @default.
- W2031925275 created "2016-06-24" @default.
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- W2031925275 date "2008-05-15" @default.
- W2031925275 modified "2023-10-14" @default.
- W2031925275 title "A New General Methodology for the Syntheses of End-Functional Polyisobutylenes by Nucleophilic Substitution Reactions" @default.
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- W2031925275 doi "https://doi.org/10.1021/ma7027209" @default.
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