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- W2031976945 abstract "The kinetics of the ion transfer across the liquid|liquid interface is studied by means of a thin film-modified electrode in combination with square-wave voltammetry. The thin film-modified electrode consists of an edge plane pyrolytic graphite electrode covered with a thin film of a water immiscible electroinactive organic solvent containing a neutral redox probe and a suitable electrolyte. The overall electrochemical process, proceeding as a coupled electron–ion transfer reaction, is controlled either by the electron transfer across the graphite electrode|organic solvent or by the ion transfer across the organic solvent|aqueous electrolyte interface. The theoretical model enabling to distinguish the rate limiting step is developed. The theory is used to measure the kinetics of ClO4-,NO3-, Cl−, SCN−, Na+, K+, (CH3)4N+, and (C4H9)4N+ across the water|nitrobenzene interface utilizing lutetium bis(tetra-tert-butylphthalocyaninato) as a redox probe." @default.
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- W2031976945 date "2005-11-01" @default.
- W2031976945 modified "2023-10-11" @default.
- W2031976945 title "Studying the kinetics of the ion transfer across the liquid|liquid interface by means of thin film-modified electrodes" @default.
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- W2031976945 doi "https://doi.org/10.1016/j.elecom.2005.08.005" @default.
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