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- W2031988929 abstract "An approach, employing the concept of molecular connectivity index of the third degree of graph theory, has been developed to evaluate molar excess enthalpy, HE(T1, x), and molar excess volume VE(T1, x) of any kind of binary mixture (liquid as well as gaseous) of non-electrolytes, and the calculated HE(T1, x) or VE(T1, x) values agree well with their corresponding experimental values. This approach has also been extended to study the effect of temperature and pressure on HE(T1, x) and VE(T1, x) data of any kind of binary mixture of non-electrolytes, and the calculated HE(T2, x, P = 1 atm), HE(T2, x, P2 ≠ 1 atm), VE(T2, x, P2 = 1 atm) and VE(T2, x, P2 ≠ 1 atm) values, obtained from HE(T1, x, P = 1 atm) or VE(T1, x, P = 1 atm) data, compare well with their corresponding experimental values. The approach has further been utilized to evaluate specific volumes ν(T1, x, P2 ⪢ 1 atm) of pure compounds as well as their mixtures when ν(T1, P = 1 atm) or ν(T1, x, P = 1 atm) data are available; the calculated ν(T1, x) and ν(T1, x, P2) values again compare well (within 5% at the worst) with their corresponding experimental values." @default.
- W2031988929 created "2016-06-24" @default.
- W2031988929 creator A5033497990 @default.
- W2031988929 date "1983-08-01" @default.
- W2031988929 modified "2023-10-16" @default.
- W2031988929 title "Topological aspects of the effect of temperature and pressure on the thermodynamics of binary mixtures of non-electrolytes" @default.
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- W2031988929 doi "https://doi.org/10.1016/0040-6031(93)85021-z" @default.
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