Matches in SemOpenAlex for { <https://semopenalex.org/work/W2031999618> ?p ?o ?g. }
- W2031999618 endingPage "3510" @default.
- W2031999618 startingPage "3502" @default.
- W2031999618 abstract "An organometallic building block strategy was employed to investigate the magnetic properties of a LnIII organometallic single-ion magnet (SIM) and subsequent single-molecule magnet (SMM) after coupling two of the monomeric units. New homoleptic DyIIICOT″2 and LnIII2COT″3 (Ln = Gd, Dy) complexes have been synthesized. DFT calculations of the bimetallic DyIII complex indicate strong metal–ligand covalency and uneven donation to the DyIII ions by the terminal and internal COT″2– (cyclooctatetraenide) rings that correlate with the respective bond distances. Interestingly, the studies also point to a weak covalent interaction between the metal centers, despite a large separation. The ac susceptibility data indicates that both DyIIICOT″2 and DyIII2COT″3 act as an SIM and an SMM, respectively, with complex multiple relaxation mechanisms. Ab initio calculations reveal the direction of the magnetic anisotropic axis is not perpendicular to the planar COT″ rings for both DyIIICOT″2 and DyIII2COT″3 complexes due to the presence of trimethylsilyl groups on the COT″ rings. If these bulky groups are removed, the calculations predict reorientation of the anisotropic axis can be achieved." @default.
- W2031999618 created "2016-06-24" @default.
- W2031999618 creator A5026079697 @default.
- W2031999618 creator A5026611636 @default.
- W2031999618 creator A5027944192 @default.
- W2031999618 creator A5029931677 @default.
- W2031999618 creator A5036142659 @default.
- W2031999618 creator A5066675504 @default.
- W2031999618 creator A5067607322 @default.
- W2031999618 date "2013-02-22" @default.
- W2031999618 modified "2023-10-16" @default.
- W2031999618 title "An Organometallic Building Block Approach To Produce a Multidecker 4<i>f</i> Single-Molecule Magnet" @default.
- W2031999618 cites W1650728208 @default.
- W2031999618 cites W1963665703 @default.
- W2031999618 cites W1968532525 @default.
- W2031999618 cites W1970326168 @default.
- W2031999618 cites W1970881901 @default.
- W2031999618 cites W1971275446 @default.
- W2031999618 cites W1975798060 @default.
- W2031999618 cites W1976889899 @default.
- W2031999618 cites W1978239898 @default.
- W2031999618 cites W1979956099 @default.
- W2031999618 cites W1984729544 @default.
- W2031999618 cites W1990419319 @default.
- W2031999618 cites W2002133214 @default.
- W2031999618 cites W2021050313 @default.
- W2031999618 cites W2023271753 @default.
- W2031999618 cites W2025031859 @default.
- W2031999618 cites W2025715829 @default.
- W2031999618 cites W2026916337 @default.
- W2031999618 cites W2030562751 @default.
- W2031999618 cites W2033050479 @default.
- W2031999618 cites W2036265717 @default.
- W2031999618 cites W2038409508 @default.
- W2031999618 cites W2043260720 @default.
- W2031999618 cites W2045952721 @default.
- W2031999618 cites W2049189395 @default.
- W2031999618 cites W2050535345 @default.
- W2031999618 cites W2052454557 @default.
- W2031999618 cites W2053386380 @default.
- W2031999618 cites W2057602558 @default.
- W2031999618 cites W2058210956 @default.
- W2031999618 cites W2065653048 @default.
- W2031999618 cites W2070150426 @default.
- W2031999618 cites W2071236931 @default.
- W2031999618 cites W2076288658 @default.
- W2031999618 cites W2084043287 @default.
- W2031999618 cites W2084239075 @default.
- W2031999618 cites W2091711229 @default.
- W2031999618 cites W2096126273 @default.
- W2031999618 cites W2100113961 @default.
- W2031999618 cites W2100247001 @default.
- W2031999618 cites W2105221960 @default.
- W2031999618 cites W2105360570 @default.
- W2031999618 cites W2106321593 @default.
- W2031999618 cites W2108374495 @default.
- W2031999618 cites W2110424924 @default.
- W2031999618 cites W2125587597 @default.
- W2031999618 cites W2131350133 @default.
- W2031999618 cites W2134324457 @default.
- W2031999618 cites W2135129562 @default.
- W2031999618 cites W2135712245 @default.
- W2031999618 cites W2138958055 @default.
- W2031999618 cites W2140284801 @default.
- W2031999618 cites W2143981217 @default.
- W2031999618 cites W2145776938 @default.
- W2031999618 cites W2146099614 @default.
- W2031999618 cites W2158280031 @default.
- W2031999618 cites W2166972749 @default.
- W2031999618 cites W2312573082 @default.
- W2031999618 cites W2318964624 @default.
- W2031999618 cites W2320060235 @default.
- W2031999618 cites W2330501265 @default.
- W2031999618 cites W4241476540 @default.
- W2031999618 cites W4250451065 @default.
- W2031999618 doi "https://doi.org/10.1021/ja310642h" @default.
- W2031999618 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23391235" @default.
- W2031999618 hasPublicationYear "2013" @default.
- W2031999618 type Work @default.
- W2031999618 sameAs 2031999618 @default.
- W2031999618 citedByCount "184" @default.
- W2031999618 countsByYear W20319996182013 @default.
- W2031999618 countsByYear W20319996182014 @default.
- W2031999618 countsByYear W20319996182015 @default.
- W2031999618 countsByYear W20319996182016 @default.
- W2031999618 countsByYear W20319996182017 @default.
- W2031999618 countsByYear W20319996182018 @default.
- W2031999618 countsByYear W20319996182019 @default.
- W2031999618 countsByYear W20319996182020 @default.
- W2031999618 countsByYear W20319996182021 @default.
- W2031999618 countsByYear W20319996182022 @default.
- W2031999618 countsByYear W20319996182023 @default.
- W2031999618 crossrefType "journal-article" @default.
- W2031999618 hasAuthorship W2031999618A5026079697 @default.
- W2031999618 hasAuthorship W2031999618A5026611636 @default.
- W2031999618 hasAuthorship W2031999618A5027944192 @default.
- W2031999618 hasAuthorship W2031999618A5029931677 @default.
- W2031999618 hasAuthorship W2031999618A5036142659 @default.