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- W2032016184 abstract "Absolute cross sections and rate constants for the endothermic proton transfer reaction of rotationally state selected HBr + ions with CO 2 were measured as a function of the rotational energy for different center-of-mass (c.m.) collision energies. State selection of HBr + ions was achieved via a (2+1) resonance enhanced multiphoton ionization (REMPI) process. By choosing different pump lines the mean rotational energy of HBr + was varied from 1.6 to 25.9 meV. All experiments were performed in a linear ion guide apparatus. Collision energies considered ranged from 0.28 to 0.85 eV (c.m.). At the highest collision energies the cross section decreases by about 60% from 10 Å 2 to 4 Å 2 with increasing rotational energy. In contrast to that, at the lowest collision energies the cross section was about 2.5 Å 2 , independent of the rotational energy." @default.
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- W2032016184 date "2007-05-01" @default.
- W2032016184 modified "2023-10-14" @default.
- W2032016184 title "Rotational Dependence of the Proton Transfer Reaction HBr+ (N+) + CO2 → HOCO+ + Br" @default.
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- W2032016184 doi "https://doi.org/10.1524/zpch.2007.221.5.571" @default.
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