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• W2032029599 abstract "Abstract The degradation process of ifosfamide in aqueous solution at 50°C was investigated at different concentrations, different pH ranges (3.6–9.8), different molarity and constant ionic strength. The observed rate obtained by measuring the remaining intact ifosfamide was shown to observe first-order kinetics and was shown to be a specific acid and base catalysis. The pH rate profile in buffer solutions showed a plateau between pH 4 and 7.9. In order to determine the effect of temperature, the kinetic process at four temperatures (40, 50, 60 and 70°C) was studied. The apparent heat of activation for ifosfamide degradation in solution was found to be 118 kJ/mol and by application of the Arrhenius equation the stability at 25°C (k25) and the shelf-life (t90) has been predicted. The agreement between the thin-layer chromatography (TLC), nuclear magnetic resonance (NMR) and high performance liquid chromatography (HPLC) supports the hypothesis presented concerning the reactions involved in the degradation of ifosfamide solutions." @default.
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• W2032029599 date "1996-08-01" @default.
• W2032029599 modified "2023-10-18" @default.
• W2032029599 title "Degradation kinetics of ifosfamide in aqueous solution" @default.
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• W2032029599 doi "https://doi.org/10.1016/0378-5173(96)04629-7" @default.
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