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- W2032029944 abstract "Conformation change occurring during the formation of the liquid crystalline phase was investigated by using the in situ Fourier transform infrared spectroscopy. An isotropic glass of a random liquid crystalline copolyester consisting of 60 mol% p-hydroxybenzoic acid/40 mol% ethylene terephthalate was prepared with the cast from a solution and was heated from the room temperature up to 300°C. The onset of the transformation from the gauche conformers to the trans conformers of the ethylene glycol group was observed at ca. 60°C. The change in packing was indicated by the change in the intensity of the bands assignable to the aromatic rings around 150°C. Liquid crystalline phase formation observed with the optical method started to occur at ca. 200°C in association with the loss of the packing." @default.
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- W2032029944 date "1999-04-01" @default.
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- W2032029944 title "In Situ Infrared Spectroscopic Study on Liquid Crystalline Phase Formation of a Random Copolyester Consisting of 60 mol% p-Hydroxybenzoic Acid/40 mol% Ethylene Terephthalate" @default.
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- W2032029944 doi "https://doi.org/10.1295/polymj.31.375" @default.
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