Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032055912> ?p ?o ?g. }
- W2032055912 endingPage "2350" @default.
- W2032055912 startingPage "2344" @default.
- W2032055912 abstract "In an aprotic medium and at a Pt electrode, cis- and trans-[Re(NCR)2(Ph2PCH2CH2PPh2)2]+ (cis+ and trans+, respectively; R = aryl or alkyl) undergo two successive single-electron oxidations to form the 17-electron (cis2+ or trans2+) and 16-electron (cis3+ or trans3+) derivatives. The cis3+ complexes isomerize to the corresponding trans3+ complexes which undergo a slower decomposition reaction, and the rate constants (ki3+ and kdec, respectively) have been determined by kinetic analysis of the cyclic voltammetric behavior. For the aromatic nitrile complexes, both rate constants increase with the electron-withdrawing ability (Hammett's σp constant) of R. The ratios of the isomeric equilibrium constants (cis3+ ⇄ trans3+, cis2+ ⇄ trans2+, and cis+ ⇄ trans+), for the aromatic nitrile complexes, also increase with σp, the thermodynamic gain in favor of the trans isomer is much higher upon the first oxidation than upon the second one, and it decreases with the increase of σp (higher sensitivity of the energy of t..." @default.
- W2032055912 created "2016-06-24" @default.
- W2032055912 creator A5007246226 @default.
- W2032055912 creator A5040684087 @default.
- W2032055912 creator A5063013653 @default.
- W2032055912 creator A5070100647 @default.
- W2032055912 creator A5084226540 @default.
- W2032055912 date "1998-04-28" @default.
- W2032055912 modified "2023-10-18" @default.
- W2032055912 title "Electron-Transfer-Induced Geometrical Isomerization of the Dinitrile Complexes <i>cis</i>-[Re(NCR)<sub>2</sub>(Ph<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>PPh<sub>2</sub>)<sub>2</sub>][BF<sub>4</sub>] (R = Aryl, Alkyl): Rates, Mechanism, and Ligand Effects" @default.
- W2032055912 cites W1970360461 @default.
- W2032055912 cites W1971934118 @default.
- W2032055912 cites W1975705223 @default.
- W2032055912 cites W1978841490 @default.
- W2032055912 cites W1987838178 @default.
- W2032055912 cites W1988421400 @default.
- W2032055912 cites W1990274573 @default.
- W2032055912 cites W2000110275 @default.
- W2032055912 cites W2000302216 @default.
- W2032055912 cites W2001688963 @default.
- W2032055912 cites W2008634271 @default.
- W2032055912 cites W2014455084 @default.
- W2032055912 cites W2015632591 @default.
- W2032055912 cites W2016062868 @default.
- W2032055912 cites W2020234775 @default.
- W2032055912 cites W2023141927 @default.
- W2032055912 cites W2028313547 @default.
- W2032055912 cites W2036596319 @default.
- W2032055912 cites W2037270587 @default.
- W2032055912 cites W2046735472 @default.
- W2032055912 cites W2047494966 @default.
- W2032055912 cites W2070245693 @default.
- W2032055912 cites W2071669157 @default.
- W2032055912 cites W2072394907 @default.
- W2032055912 cites W2082172700 @default.
- W2032055912 cites W2082415368 @default.
- W2032055912 cites W2083532368 @default.
- W2032055912 cites W2084598564 @default.
- W2032055912 cites W2087310773 @default.
- W2032055912 cites W2088376114 @default.
- W2032055912 cites W2095435500 @default.
- W2032055912 cites W2167695570 @default.
- W2032055912 cites W2317914744 @default.
- W2032055912 cites W2949668589 @default.
- W2032055912 cites W2950731700 @default.
- W2032055912 cites W2951273512 @default.
- W2032055912 cites W2952120822 @default.
- W2032055912 cites W3004973414 @default.
- W2032055912 cites W3138465309 @default.
- W2032055912 cites W4253261881 @default.
- W2032055912 doi "https://doi.org/10.1021/ic971257+" @default.
- W2032055912 hasPublicationYear "1998" @default.
- W2032055912 type Work @default.
- W2032055912 sameAs 2032055912 @default.
- W2032055912 citedByCount "24" @default.
- W2032055912 countsByYear W20320559122012 @default.
- W2032055912 countsByYear W20320559122016 @default.
- W2032055912 countsByYear W20320559122022 @default.
- W2032055912 crossrefType "journal-article" @default.
- W2032055912 hasAuthorship W2032055912A5007246226 @default.
- W2032055912 hasAuthorship W2032055912A5040684087 @default.
- W2032055912 hasAuthorship W2032055912A5063013653 @default.
- W2032055912 hasAuthorship W2032055912A5070100647 @default.
- W2032055912 hasAuthorship W2032055912A5084226540 @default.
- W2032055912 hasConcept C121332964 @default.
- W2032055912 hasConcept C123669783 @default.
- W2032055912 hasConcept C126661725 @default.
- W2032055912 hasConcept C147120987 @default.
- W2032055912 hasConcept C147597530 @default.
- W2032055912 hasConcept C161790260 @default.
- W2032055912 hasConcept C173608175 @default.
- W2032055912 hasConcept C178790620 @default.
- W2032055912 hasConcept C185592680 @default.
- W2032055912 hasConcept C2776175482 @default.
- W2032055912 hasConcept C41008148 @default.
- W2032055912 hasConcept C62520636 @default.
- W2032055912 hasConcept C71240020 @default.
- W2032055912 hasConcept C75473681 @default.
- W2032055912 hasConcept C8010536 @default.
- W2032055912 hasConceptScore W2032055912C121332964 @default.
- W2032055912 hasConceptScore W2032055912C123669783 @default.
- W2032055912 hasConceptScore W2032055912C126661725 @default.
- W2032055912 hasConceptScore W2032055912C147120987 @default.
- W2032055912 hasConceptScore W2032055912C147597530 @default.
- W2032055912 hasConceptScore W2032055912C161790260 @default.
- W2032055912 hasConceptScore W2032055912C173608175 @default.
- W2032055912 hasConceptScore W2032055912C178790620 @default.
- W2032055912 hasConceptScore W2032055912C185592680 @default.
- W2032055912 hasConceptScore W2032055912C2776175482 @default.
- W2032055912 hasConceptScore W2032055912C41008148 @default.
- W2032055912 hasConceptScore W2032055912C62520636 @default.
- W2032055912 hasConceptScore W2032055912C71240020 @default.
- W2032055912 hasConceptScore W2032055912C75473681 @default.
- W2032055912 hasConceptScore W2032055912C8010536 @default.
- W2032055912 hasIssue "10" @default.
- W2032055912 hasLocation W20320559121 @default.
- W2032055912 hasOpenAccess W2032055912 @default.
- W2032055912 hasPrimaryLocation W20320559121 @default.