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- W2032057939 abstract "Abstract The mechanism of isomerization of Δ8to Δ7cholestenol is studied in rat liver homogenates incubated with (±)[2-3H2]-mevalonic acid lactone. The isolated 5α-cholest-7-en-3β-ol and cholesta-5,7-dien-3β-ol were both transformed into 5α-cholesta-7,9(11)-dien-3β-ol; the latter isolated sterol was also converted into 3,8-dioxo-7,8-seco-5α-cholestan-7-oic acid. Exchange experiments with deuterium and comparison of the radioactivities of the two sterols with those of their transformation products show that the Δ8to Δ7isomerization does not involve an intramolecular hydride shift from the 7- to 9α- position." @default.
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- W2032057939 date "1968-03-01" @default.
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- W2032057939 title "The biological conversion of 5α-cholest-8-en-3β-ol to 5α-cholest-7-en-3β-ol in the biosynthesis of cholesterol" @default.
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- W2032057939 doi "https://doi.org/10.1016/s0039-128x(68)80141-2" @default.
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