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- W2032060166 abstract "Ultrasonic speed, u, and excess volume, VE, measurements have been made for mixtures of pyrrolidin-2-one +n-alkanol (C6–C10) over the entire composition range at 303.15 K. VE values are negative for pyrrolidin-2-one + hexanol, S-shaped for heptanol and completely positive for rest of the mixtures and increase in the order hexanol < heptanol < octanol < nonanol < decanol. The VE results have been used to calculate the excess partial molar volumes of the components and have also been analysed using Prigogine–Flory–Patterson theory which divides VE into three contributions viz. the interactional, free volume and P* effects. It has been found that the dominant role is played by the interactional term which is the main parameter for deciding the sign and magnitude of excess volumes for pyrrolidin-2-one + alkanol (C6–C10) mixtures." @default.
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- W2032060166 date "1996-01-01" @default.
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- W2032060166 title "Partial molar volumes and isentropic compressibilities of mixtures of γ-butyrolactam (n= 5) with higher alkanols" @default.
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- W2032060166 doi "https://doi.org/10.1039/ft9969204463" @default.
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