FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032064889> ?p ?o ?g. }

• W2032064889 endingPage "160" @default.
• W2032064889 startingPage "152" @default.
• W2032064889 abstract "The NCO-functionalization of methyl cellulose with HMDI and its application to chemically gel the castor oil is explored in this work by analyzing the influence of functionalization degree on the rheological and thermogravimetric behavior of resulting chemical oleogels. With this aim, different methyl cellulose chemical modifications were achieved by limiting the proportion of HMDI and, subsequently, oleogels were obtained by dispersing these polymers in castor oil and promoting the reaction between those biopolymers and the hydroxyl groups located in the ricinoleic fatty acid chain. NCO-functionalized methyl cellulose-based oleogels were characterized from themogravimetric and rheological points of view. Suitable thermal resistance and rheological characteristics were found in order to propose these oleogels as promising bio-based alternatives to traditional lubricating greases based on non-renewable resources. In general, NCO-functionalized methyl cellulose thermally decomposed in three main steps whereas resulting oleogels thermal decomposition takes place in one main single stage which comprises the thermal degradation of both the polymer and the castor oil. Temperature range for thermal degradation is broadened when using highly NCO-functionalized methyl cellulose. A cross-linked viscoelastic gel was obtained with methyl cellulose functionalized in a relatively low degree (around 6% NCO molar content). The rheological properties of highly functionalized methyl cellulose-based oleogels evolve during several months of aging, but mainly during the first week, due to the progress of the reaction between NCO functional groups and castor oil OH groups. SAOS functions analyzed and oleogel relative elasticity increase with the functionalization degree. Oleogel linear viscoelastic response is also extremely dependent on NCO-functionalized methyl cellulose concentration." @default.
• W2032064889 created "2016-06-24" @default.
• W2032064889 creator A5004986843 @default.
• W2032064889 creator A5007897987 @default.
• W2032064889 creator A5027570780 @default.
• W2032064889 creator A5086207873 @default.
• W2032064889 date "2013-10-01" @default.
• W2032064889 modified "2023-10-15" @default.
• W2032064889 title "Rheology and thermal degradation of isocyanate-functionalized methyl cellulose-based oleogels" @default.
• W2032064889 cites W1965164563 @default.
• W2032064889 cites W1965829719 @default.
• W2032064889 cites W1966845013 @default.
• W2032064889 cites W1969765153 @default.
• W2032064889 cites W1974896454 @default.
• W2032064889 cites W1980872749 @default.
• W2032064889 cites W1981961547 @default.
• W2032064889 cites W1982224927 @default.
• W2032064889 cites W1985486539 @default.
• W2032064889 cites W1991492722 @default.
• W2032064889 cites W1994429337 @default.
• W2032064889 cites W1998935458 @default.
• W2032064889 cites W2002302214 @default.
• W2032064889 cites W2002363341 @default.
• W2032064889 cites W2007944147 @default.
• W2032064889 cites W2015970478 @default.
• W2032064889 cites W2025505225 @default.
• W2032064889 cites W2026776687 @default.
• W2032064889 cites W2031330212 @default.
• W2032064889 cites W2034023606 @default.
• W2032064889 cites W2034657159 @default.
• W2032064889 cites W2037875712 @default.
• W2032064889 cites W2044849414 @default.
• W2032064889 cites W2046602725 @default.
• W2032064889 cites W2046954824 @default.
• W2032064889 cites W2051154154 @default.
• W2032064889 cites W2051217743 @default.
• W2032064889 cites W2062653267 @default.
• W2032064889 cites W2064468025 @default.
• W2032064889 cites W2065341427 @default.
• W2032064889 cites W2065909935 @default.
• W2032064889 cites W2071671487 @default.
• W2032064889 cites W2073561875 @default.
• W2032064889 cites W2077557935 @default.
• W2032064889 cites W2081575430 @default.
• W2032064889 cites W2089312402 @default.
• W2032064889 cites W2095361409 @default.
• W2032064889 cites W2115152651 @default.
• W2032064889 cites W2127307165 @default.
• W2032064889 cites W2137273697 @default.
• W2032064889 cites W2145798044 @default.
• W2032064889 cites W2148638142 @default.
• W2032064889 cites W2148932544 @default.
• W2032064889 cites W2154232844 @default.
• W2032064889 cites W2161174878 @default.
• W2032064889 cites W2334278443 @default.
• W2032064889 cites W2335193443 @default.
• W2032064889 cites W1975592668 @default.
• W2032064889 doi "https://doi.org/10.1016/j.carbpol.2013.04.104" @default.
• W2032064889 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23987329" @default.
• W2032064889 hasPublicationYear "2013" @default.
• W2032064889 type Work @default.
• W2032064889 sameAs 2032064889 @default.
• W2032064889 citedByCount "42" @default.
• W2032064889 countsByYear W20320648892013 @default.
• W2032064889 countsByYear W20320648892014 @default.
• W2032064889 countsByYear W20320648892015 @default.
• W2032064889 countsByYear W20320648892016 @default.
• W2032064889 countsByYear W20320648892017 @default.
• W2032064889 countsByYear W20320648892018 @default.
• W2032064889 countsByYear W20320648892019 @default.
• W2032064889 countsByYear W20320648892020 @default.
• W2032064889 countsByYear W20320648892021 @default.
• W2032064889 countsByYear W20320648892022 @default.
• W2032064889 countsByYear W20320648892023 @default.
• W2032064889 crossrefType "journal-article" @default.
• W2032064889 hasAuthorship W2032064889A5004986843 @default.
• W2032064889 hasAuthorship W2032064889A5007897987 @default.
• W2032064889 hasAuthorship W2032064889A5027570780 @default.
• W2032064889 hasAuthorship W2032064889A5086207873 @default.
• W2032064889 hasConcept C115537861 @default.
• W2032064889 hasConcept C127413603 @default.
• W2032064889 hasConcept C159985019 @default.
• W2032064889 hasConcept C178790620 @default.
• W2032064889 hasConcept C185592680 @default.
• W2032064889 hasConcept C186541917 @default.
• W2032064889 hasConcept C188027245 @default.
• W2032064889 hasConcept C192562407 @default.
• W2032064889 hasConcept C200990466 @default.
• W2032064889 hasConcept C2778229996 @default.
• W2032064889 hasConcept C2779251873 @default.
• W2032064889 hasConcept C42360764 @default.
• W2032064889 hasConcept C521977710 @default.
• W2032064889 hasConceptScore W2032064889C115537861 @default.
• W2032064889 hasConceptScore W2032064889C127413603 @default.
• W2032064889 hasConceptScore W2032064889C159985019 @default.
• W2032064889 hasConceptScore W2032064889C178790620 @default.
• W2032064889 hasConceptScore W2032064889C185592680 @default.
• W2032064889 hasConceptScore W2032064889C186541917 @default.

• next