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- W2032065531 abstract "The formation of nitric oxide myoglobin (nitrosylmyoglobin) was followed in buffered solutions in which the concentrations of ascorbate, nitrite, chloride, myoglobin and hydrogen ion were varied systematically to determine their effect on the rate constants. The rate of formation of nitrosylmyoglobin was zero order with respect to the pigment. The orders for the other reactants were determined by plotting the zero order rate constants as functions of varying orders of each reagent to determine which order gave a linear plot. The results were used to develop a mechanism and a mathematical expression for the reaction. Two reaction sequences involving different nitrosating species were involved; 1, direct action of nitrous acid and 2, the formation of nitrosyl chloride. Both species then nitrosated ascorbate and ascorbic acid, by different mechanisms. The nitric oxide for nitrosylmyoglobin formation came from the nitrosated ascorbate." @default.
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- W2032065531 date "1994-02-01" @default.
- W2032065531 modified "2023-09-26" @default.
- W2032065531 title "KINETIC ANALYLSIS OF THE FORMATION OF NITROSYLMYOGLOBIN" @default.
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- W2032065531 doi "https://doi.org/10.1111/j.1745-4573.1994.tb00515.x" @default.
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