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- W2032066247 abstract "The viscoelastic relaxations of four copolymers of ethylene and 1-octadecene, with different comonomer contents, synthesized with a metallocene catalyst, have been analysed and compared to those of the corresponding polyethylene homopolymer. Similar to other ethylene copolymers, the temperature for α relaxation decreases with the increase in the comonomer content, attributed to the reduction of the crystal size. In fact, a linear relation has been found between the temperature location of α relaxation and the crystal thickness estimated from the SAXS long spacing. However, the position of β relaxation experiences very little dependence with the comonomer content and it overlaps to α relaxation for the higher comonomer contents. As to γ relaxation, there is also a clear effect of the comonomer content on the breadth and on the location of this relaxation." @default.
- W2032066247 created "2016-06-24" @default.
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- W2032066247 date "2002-01-01" @default.
- W2032066247 modified "2023-10-11" @default.
- W2032066247 title "Viscoelastic relaxations in poly(ethylene-co-1-octadecene) synthesized by a metallocene catalyst" @default.
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- W2032066247 doi "https://doi.org/10.1016/s0032-3861(02)00611-0" @default.
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