Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032066857> ?p ?o ?g. }
Showing items 1 to 80 of
80
with 100 items per page.
- W2032066857 endingPage "3229" @default.
- W2032066857 startingPage "3220" @default.
- W2032066857 abstract "The crystal and molecular structure of unsym 1 - fac -Λ-(δ, chair)-( S )-[Co(aepn)( S )-Asp]ClO 4 ( trans -6,6) was solved by the heavy atom method. The positions of the non-hydrogen atoms and their anisotropic temperature parameters were refined on the basis of 1 935 observed reflections, yielding values of R = 0.121 and wR = 0.117, affected by the undertermined position of the oxygen atoms in the ClO 4 - > anion. The substance crystallizes in the orthorhombic system with space group P 2 1 2 1 2 1 ; Z = 4, a = 9.664(1), b = 11.805(1), c = 13.966(2) Å. The secondary atom of the triamine has S configuration, the conformation of the five-membered chelate ring approaches that of the asymmetrical δ envelope and the six-membered ring has chair configuration. Both conformations are deformed. The donor atoms deviate from the defined planes and thus form further sources of chirality (λ) contributing to the optical activity of the isomer. These deviations lead to the similarity of the CD spectra of the isomers." @default.
- W2032066857 created "2016-06-24" @default.
- W2032066857 creator A5017393082 @default.
- W2032066857 creator A5017791953 @default.
- W2032066857 creator A5024075651 @default.
- W2032066857 creator A5071506295 @default.
- W2032066857 creator A5079450649 @default.
- W2032066857 date "1989-01-01" @default.
- W2032066857 modified "2023-09-28" @default.
- W2032066857 title "The crystal and molecular structure of configurationally chiral unsym-fac-[N-(2-aminoethyl)-1,3-diaminopropane-(S)-aspartato]cobalt(III) perchlorate with dominating vicinal effect in its circular dichroism" @default.
- W2032066857 doi "https://doi.org/10.1135/cccc19893220" @default.
- W2032066857 hasPublicationYear "1989" @default.
- W2032066857 type Work @default.
- W2032066857 sameAs 2032066857 @default.
- W2032066857 citedByCount "1" @default.
- W2032066857 crossrefType "journal-article" @default.
- W2032066857 hasAuthorship W2032066857A5017393082 @default.
- W2032066857 hasAuthorship W2032066857A5017791953 @default.
- W2032066857 hasAuthorship W2032066857A5024075651 @default.
- W2032066857 hasAuthorship W2032066857A5071506295 @default.
- W2032066857 hasAuthorship W2032066857A5079450649 @default.
- W2032066857 hasConcept C112887158 @default.
- W2032066857 hasConcept C115624301 @default.
- W2032066857 hasConcept C121332964 @default.
- W2032066857 hasConcept C121349320 @default.
- W2032066857 hasConcept C124668440 @default.
- W2032066857 hasConcept C145148216 @default.
- W2032066857 hasConcept C178790620 @default.
- W2032066857 hasConcept C185592680 @default.
- W2032066857 hasConcept C20621625 @default.
- W2032066857 hasConcept C2780378348 @default.
- W2032066857 hasConcept C2780709120 @default.
- W2032066857 hasConcept C32909587 @default.
- W2032066857 hasConcept C37243968 @default.
- W2032066857 hasConcept C52703039 @default.
- W2032066857 hasConcept C62520636 @default.
- W2032066857 hasConcept C6652555 @default.
- W2032066857 hasConcept C71240020 @default.
- W2032066857 hasConcept C7602139 @default.
- W2032066857 hasConcept C8010536 @default.
- W2032066857 hasConceptScore W2032066857C112887158 @default.
- W2032066857 hasConceptScore W2032066857C115624301 @default.
- W2032066857 hasConceptScore W2032066857C121332964 @default.
- W2032066857 hasConceptScore W2032066857C121349320 @default.
- W2032066857 hasConceptScore W2032066857C124668440 @default.
- W2032066857 hasConceptScore W2032066857C145148216 @default.
- W2032066857 hasConceptScore W2032066857C178790620 @default.
- W2032066857 hasConceptScore W2032066857C185592680 @default.
- W2032066857 hasConceptScore W2032066857C20621625 @default.
- W2032066857 hasConceptScore W2032066857C2780378348 @default.
- W2032066857 hasConceptScore W2032066857C2780709120 @default.
- W2032066857 hasConceptScore W2032066857C32909587 @default.
- W2032066857 hasConceptScore W2032066857C37243968 @default.
- W2032066857 hasConceptScore W2032066857C52703039 @default.
- W2032066857 hasConceptScore W2032066857C62520636 @default.
- W2032066857 hasConceptScore W2032066857C6652555 @default.
- W2032066857 hasConceptScore W2032066857C71240020 @default.
- W2032066857 hasConceptScore W2032066857C7602139 @default.
- W2032066857 hasConceptScore W2032066857C8010536 @default.
- W2032066857 hasIssue "12" @default.
- W2032066857 hasLocation W20320668571 @default.
- W2032066857 hasOpenAccess W2032066857 @default.
- W2032066857 hasPrimaryLocation W20320668571 @default.
- W2032066857 hasRelatedWork W2013979702 @default.
- W2032066857 hasRelatedWork W2017252092 @default.
- W2032066857 hasRelatedWork W2028104741 @default.
- W2032066857 hasRelatedWork W2057723176 @default.
- W2032066857 hasRelatedWork W2063401985 @default.
- W2032066857 hasRelatedWork W2072417293 @default.
- W2032066857 hasRelatedWork W2093432144 @default.
- W2032066857 hasRelatedWork W2378634178 @default.
- W2032066857 hasRelatedWork W2623063059 @default.
- W2032066857 hasRelatedWork W2788975530 @default.
- W2032066857 hasVolume "54" @default.
- W2032066857 isParatext "false" @default.
- W2032066857 isRetracted "false" @default.
- W2032066857 magId "2032066857" @default.
- W2032066857 workType "article" @default.