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- W2032067034 abstract "Quantum-mechanical and semiclassical molecular-orbital expansion methods are employed to investigate a single-electron-capture mechanism in ${mathrm{N}}^{5+}$+H collisions in the energy range from 10 meV/amu to 10 keV/amu. The dominant electron-capture channels in the entire regime are found to be ${mathrm{N}}^{4+}$(4s), ${mathrm{N}}^{4+}$(4p), and to some extent ${mathrm{N}}^{4+}$(4d). The ${mathrm{N}}^{4+}$(4f) channel is found to make small contributions at any energy because of its near diabaticity with respect to the initial channel. Agreement for total and n-shell captures with recent measurements is excellent in the entire energy regime, and agreement for l-shell capture with measurements is reasonable for most cases. Furthermore, several shape resonances due to rovibrational states of the transient quasimolecule are found below 1 eV, and a large, broad structure arising from trajectory effects due to the weak attractive polarization potential is found below 60 meV/amu. The origins of differences between the present results and the measurements and other theoretical calculations are also discussed." @default.
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- W2032067034 date "1991-08-01" @default.
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- W2032067034 title "Electron capture in collisions ofN5+ions with H atoms from the meV to keV energy regions" @default.
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- W2032067034 doi "https://doi.org/10.1103/physreva.44.1659" @default.
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