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- W2032069013 abstract "The steady-state optical and charge transport properties of the anionic polythiophene, poly[3-(potassium-4-butanoate)thiophene-2,5-diyl], are reported. The degree of interchain aggregation in solution and in the film state can be controlled by solution processing conditions and the introduction of bulky organic counterions. Disruption of interchain contacts leads to significant changes in the absorption and emission properties. Scanning probe microscopy reveals various surface morphologies, depending on the solution history. Attempts to determine electronic charge carrier mobilities by using steady-state current−voltage (I−V) measurements using hole-only diodes gives rise to light-emitting electrochemical cell behavior, indicating ion motion and/or redistribution within the films. The use of a pulsed I−V method operating at frequencies higher than the ion response times allows measurements of electronic carrier mobilities in hole-only diodes. Hole mobilities in films with different degrees of chain aggreg..." @default.
- W2032069013 created "2016-06-24" @default.
- W2032069013 creator A5038604576 @default.
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- W2032069013 date "2008-04-10" @default.
- W2032069013 modified "2023-09-30" @default.
- W2032069013 title "Effect of Aggregation on the Optical and Charge Transport Properties of an Anionic Conjugated Polyelectrolyte" @default.
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- W2032069013 doi "https://doi.org/10.1021/jp711462p" @default.
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