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• W2032070801 abstract "Abstract Summary: Phase separation of aqueous solutions of temperature‐responsive polymers such as poly( N ‐isopropylacrylamide) (PNiPAm) and poly( N,N ‐diethylacrylamide) (PdEA) was investigated. IR spectroscopy was proved to be a quite useful method observing changes in the hydration states of individual chemical groups of the polymers. For example, the analyses of the amide I and II bands provides important information concerning the hydrogen bonding of the CO group and the N‐H group, respectively. Changes in the CH stretching bands indicate hydration changes of the alkyl groups. In addition, molecular simulations based on quantum chemistry give a strong support to the interpretation on molecular level. Our recent progress on this subject was presented and the relationship between the molecular interactions and the macroscopic phase behaviors was discussed." @default.
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• W2032070801 date "2011-05-01" @default.
• W2032070801 modified "2023-09-25" @default.
• W2032070801 title "Hydration of Temperature-Responsive Polymers Observed by IR Spectroscopy" @default.
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• W2032070801 doi "https://doi.org/10.1002/masy.201150509" @default.
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