FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032074404> ?p ?o ?g. }

• W2032074404 endingPage "3343" @default.
• W2032074404 startingPage "3330" @default.
• W2032074404 abstract "Femtosecond time-resolved optical-heterodyne detected Raman-induced Kerr effect spectroscopy (OHD-RIKES) is shown to be a powerful and comprehensive tool for studying the intermolecular dynamics occurring in liquids. The observed dynamics include both the underdamped, or coherent inertial motions, and the longer time scale diffusive relaxation. The inertial dynamics include phonon-like intermolecular vibrations, intermolecular collisions, and librational caging motions. Data are presented and analyzed for a series of five liquids: cyclohexane, methylcyclohexane, toluene, benzyl alcohol, and benzonitrile, listed in order of increasing polarity. We explore the effects of aromaticity (e.g., methylcyclohexane vs. toluene), symmetry reduction (cyclohexane vs methylcyclohexane), and substitution effects (e.g., substituted benzene series) on the ultrafast intermolecular dynamics, for a group of molecular liquids of similar size and volume. We analyze the intermolecular dynamics in both the time and frequency domains by means of Fourier transformations. When Fourier-transformed into the frequency domain, the OHD-RIKES ultrafast transients of the intermolecular dynamics can be directly compared with the frequency domain spectra obtained from the far-infrared absorption and depolarized Raman techniques. This is done using the Gaussian librational caging model of Lynden-Bell and Steele, which results in a power-law scaling relation between dipole and polarizability time correlation functions. Last, we use a theoretical treatment of Maroncelli and co-workers to model for some of these liquids the solvation time-correlation function for the solvation of a charge-transfer excited-state chromophore based on the measured neat solvent dynamics." @default.
• W2032074404 created "2016-06-24" @default.
• W2032074404 creator A5031315521 @default.
• W2032074404 creator A5032749422 @default.
• W2032074404 date "1996-01-01" @default.
• W2032074404 modified "2023-09-27" @default.
• W2032074404 title "Intermolecular Dynamics of Substituted Benzene and Cyclohexane Liquids, Studied by Femtosecond Nonlinear-Optical Polarization Spectroscopy" @default.
• W2032074404 cites W1517260174 @default.
• W2032074404 cites W1664683784 @default.
• W2032074404 cites W1962773290 @default.
• W2032074404 cites W1965343169 @default.
• W2032074404 cites W1968117549 @default.
• W2032074404 cites W1969434386 @default.
• W2032074404 cites W1971897294 @default.
• W2032074404 cites W1972052884 @default.
• W2032074404 cites W1975079806 @default.
• W2032074404 cites W1984750191 @default.
• W2032074404 cites W1986853233 @default.
• W2032074404 cites W1991530026 @default.
• W2032074404 cites W1999526329 @default.
• W2032074404 cites W2004268875 @default.
• W2032074404 cites W2005682313 @default.
• W2032074404 cites W2008898112 @default.
• W2032074404 cites W2011144395 @default.
• W2032074404 cites W2014135779 @default.
• W2032074404 cites W2014243239 @default.
• W2032074404 cites W2017288502 @default.
• W2032074404 cites W2017898890 @default.
• W2032074404 cites W2024860409 @default.
• W2032074404 cites W2030841140 @default.
• W2032074404 cites W2031383264 @default.
• W2032074404 cites W2035711091 @default.
• W2032074404 cites W2036563624 @default.
• W2032074404 cites W2036680166 @default.
• W2032074404 cites W2038380532 @default.
• W2032074404 cites W2038475230 @default.
• W2032074404 cites W2046342343 @default.
• W2032074404 cites W2046601068 @default.
• W2032074404 cites W2050406810 @default.
• W2032074404 cites W2051577623 @default.
• W2032074404 cites W2052117260 @default.
• W2032074404 cites W2055088168 @default.
• W2032074404 cites W2055836624 @default.
• W2032074404 cites W2056431633 @default.
• W2032074404 cites W2058604300 @default.
• W2032074404 cites W2060904744 @default.
• W2032074404 cites W2061653486 @default.
• W2032074404 cites W2065500697 @default.
• W2032074404 cites W2069618895 @default.
• W2032074404 cites W2070455862 @default.
• W2032074404 cites W2070917899 @default.
• W2032074404 cites W2071670597 @default.
• W2032074404 cites W2072836766 @default.
• W2032074404 cites W2075086388 @default.
• W2032074404 cites W2081369169 @default.
• W2032074404 cites W2087425751 @default.
• W2032074404 cites W2092780085 @default.
• W2032074404 cites W2093102045 @default.
• W2032074404 cites W2112597660 @default.
• W2032074404 cites W2130877416 @default.
• W2032074404 cites W2133013032 @default.
• W2032074404 cites W2134007496 @default.
• W2032074404 cites W2136354378 @default.
• W2032074404 cites W2137148785 @default.
• W2032074404 cites W2139029442 @default.
• W2032074404 cites W2147705945 @default.
• W2032074404 cites W2156816586 @default.
• W2032074404 cites W2158356154 @default.
• W2032074404 cites W2160172955 @default.
• W2032074404 cites W2169111063 @default.
• W2032074404 cites W2494398488 @default.
• W2032074404 cites W2915110840 @default.
• W2032074404 cites W2917024237 @default.
• W2032074404 cites W3022806437 @default.
• W2032074404 cites W3098279839 @default.
• W2032074404 cites W4247178772 @default.
• W2032074404 cites W4249161824 @default.
• W2032074404 cites W612511768 @default.
• W2032074404 cites W652315324 @default.
• W2032074404 doi "https://doi.org/10.1021/jp952073o" @default.
• W2032074404 hasPublicationYear "1996" @default.
• W2032074404 type Work @default.
• W2032074404 sameAs 2032074404 @default.
• W2032074404 citedByCount "123" @default.
• W2032074404 countsByYear W20320744042012 @default.
• W2032074404 countsByYear W20320744042014 @default.
• W2032074404 countsByYear W20320744042015 @default.
• W2032074404 countsByYear W20320744042016 @default.
• W2032074404 countsByYear W20320744042017 @default.
• W2032074404 countsByYear W20320744042018 @default.
• W2032074404 countsByYear W20320744042020 @default.
• W2032074404 countsByYear W20320744042021 @default.
• W2032074404 countsByYear W20320744042022 @default.
• W2032074404 crossrefType "journal-article" @default.
• W2032074404 hasAuthorship W2032074404A5031315521 @default.
• W2032074404 hasAuthorship W2032074404A5032749422 @default.
• W2032074404 hasConcept C121332964 @default.
• W2032074404 hasConcept C139287275 @default.

• next