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- W2032086557 abstract "Abstract In order to learn the effect of a Schiff base and the complex of Y III on the extraction of Eu III with β-diketones and on the luminescence of the extracted species, the extraction of Eu III with 2-thenoyltrifluoroacetone (Htta) and/or these Schiff bases, tris(5- t -butyl)salicylidenaminoethyl amine (H 3 L 1 ), and its Y III complex ([YL 1 ]) prepared, into CHCl 3 was examined. Further, the luminescence and excited spectra of CHCl 3 phases extracted Eu III complexes and the solutions containing tris(β-diketonato)Eu III and/or the Schiff bases were measured. On the measurement of the luminescence spectra, tris(pivaloyltrifluoroacetonato)Eu III (Eu(pta) 3 ) as well as Eu(tta) 3 was used. Synergistic effect with Htta and these Schiff bases was observed. However, proper effect of Y III was not observed. The luminescence intensity of Eu(tta) 3 at 613 nm decreased with increasing concentration of H 3 L 1 or [YL 1 ], whereas that of Eu(pta) 3 increased with increasing concentration of the ligands, but no difference between both Schiff bases was observed, because of picking up of Y III from [YL 1 ] with the interaction between [YL 1 ] and water." @default.
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- W2032086557 date "2008-02-01" @default.
- W2032086557 modified "2023-09-24" @default.
- W2032086557 title "Effect of heptadentate (N4O3) tripodal Schiff base ligand and its yttrium(III) complex on the luminescence and extraction of tris(β-diketonato)europium(III)" @default.
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- W2032086557 doi "https://doi.org/10.1016/j.jallcom.2007.04.152" @default.
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