Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032090992> ?p ?o ?g. }
- W2032090992 endingPage "226" @default.
- W2032090992 startingPage "215" @default.
- W2032090992 abstract "Using UV–Vis, resonance Raman, and EPR spectroscopy we have studied the properties of the oxygenated ferrous cytochrome P450 from Sulfolobus Solfataricus, (CYP119). The recently determined crystal structure of CYP119 is compared with other available structures of P450s, and detailed structural and spectroscopic analyses are reported. With several structural similarities to CYP102, such as in-plane iron position and a shorter iron-proximal ligand bond, CYP119 shows low-spin conformation preference in the ferric form and partially in the ferrous form at low temperatures. These structural features can explain the fast autoxidation of the oxyferrous complex of CYP119. Finally, we report the first UV–Vis and EPR spectra of the cryoradiolytically reduced oxygenated intermediate of CYP119. The primary reduced intermediate, a hydroperoxo–ferric complex of CYP119, undergoes a ‘peroxide shunt’ pathway during gradual annealing at 170–195 K and returns to the low-spin ferric form." @default.
- W2032090992 created "2016-06-24" @default.
- W2032090992 creator A5037062657 @default.
- W2032090992 creator A5057026548 @default.
- W2032090992 creator A5057938984 @default.
- W2032090992 creator A5058362235 @default.
- W2032090992 creator A5063140842 @default.
- W2032090992 creator A5067273795 @default.
- W2032090992 creator A5081446055 @default.
- W2032090992 creator A5083285181 @default.
- W2032090992 date "2001-12-01" @default.
- W2032090992 modified "2023-09-23" @default.
- W2032090992 title "Characterization of the oxygenated intermediate of the thermophilic cytochrome P450 CYP119" @default.
- W2032090992 cites W1558059901 @default.
- W2032090992 cites W1565067179 @default.
- W2032090992 cites W1965428124 @default.
- W2032090992 cites W1968172212 @default.
- W2032090992 cites W1977233538 @default.
- W2032090992 cites W1977682699 @default.
- W2032090992 cites W1978235062 @default.
- W2032090992 cites W1985562416 @default.
- W2032090992 cites W1986949928 @default.
- W2032090992 cites W1987575621 @default.
- W2032090992 cites W1987856692 @default.
- W2032090992 cites W1991026641 @default.
- W2032090992 cites W1991926626 @default.
- W2032090992 cites W1998653147 @default.
- W2032090992 cites W2000490531 @default.
- W2032090992 cites W2002678890 @default.
- W2032090992 cites W2002804207 @default.
- W2032090992 cites W2004338840 @default.
- W2032090992 cites W2013133980 @default.
- W2032090992 cites W2017643043 @default.
- W2032090992 cites W2019024614 @default.
- W2032090992 cites W2025973496 @default.
- W2032090992 cites W2034329041 @default.
- W2032090992 cites W2034754835 @default.
- W2032090992 cites W2034936033 @default.
- W2032090992 cites W2035353518 @default.
- W2032090992 cites W2049393589 @default.
- W2032090992 cites W2055117560 @default.
- W2032090992 cites W2057737797 @default.
- W2032090992 cites W2059490039 @default.
- W2032090992 cites W2061370608 @default.
- W2032090992 cites W2066594674 @default.
- W2032090992 cites W2067491528 @default.
- W2032090992 cites W2067791558 @default.
- W2032090992 cites W2068925710 @default.
- W2032090992 cites W2072623226 @default.
- W2032090992 cites W2077253713 @default.
- W2032090992 cites W2077396245 @default.
- W2032090992 cites W2078066112 @default.
- W2032090992 cites W2083352116 @default.
- W2032090992 cites W2083592891 @default.
- W2032090992 cites W2083960792 @default.
- W2032090992 cites W2089446437 @default.
- W2032090992 cites W2093905655 @default.
- W2032090992 cites W2123314190 @default.
- W2032090992 cites W2124124969 @default.
- W2032090992 cites W2140821017 @default.
- W2032090992 cites W2144860443 @default.
- W2032090992 doi "https://doi.org/10.1016/s0162-0134(01)00328-2" @default.
- W2032090992 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11744059" @default.
- W2032090992 hasPublicationYear "2001" @default.
- W2032090992 type Work @default.
- W2032090992 sameAs 2032090992 @default.
- W2032090992 citedByCount "45" @default.
- W2032090992 countsByYear W20320909922012 @default.
- W2032090992 countsByYear W20320909922013 @default.
- W2032090992 countsByYear W20320909922014 @default.
- W2032090992 countsByYear W20320909922015 @default.
- W2032090992 countsByYear W20320909922018 @default.
- W2032090992 countsByYear W20320909922019 @default.
- W2032090992 countsByYear W20320909922020 @default.
- W2032090992 countsByYear W20320909922021 @default.
- W2032090992 countsByYear W20320909922023 @default.
- W2032090992 crossrefType "journal-article" @default.
- W2032090992 hasAuthorship W2032090992A5037062657 @default.
- W2032090992 hasAuthorship W2032090992A5057026548 @default.
- W2032090992 hasAuthorship W2032090992A5057938984 @default.
- W2032090992 hasAuthorship W2032090992A5058362235 @default.
- W2032090992 hasAuthorship W2032090992A5063140842 @default.
- W2032090992 hasAuthorship W2032090992A5067273795 @default.
- W2032090992 hasAuthorship W2032090992A5081446055 @default.
- W2032090992 hasAuthorship W2032090992A5083285181 @default.
- W2032090992 hasConcept C116569031 @default.
- W2032090992 hasConcept C120665830 @default.
- W2032090992 hasConcept C121332964 @default.
- W2032090992 hasConcept C170493617 @default.
- W2032090992 hasConcept C178790620 @default.
- W2032090992 hasConcept C179104552 @default.
- W2032090992 hasConcept C185592680 @default.
- W2032090992 hasConcept C187961010 @default.
- W2032090992 hasConcept C2775832776 @default.
- W2032090992 hasConcept C2780534640 @default.
- W2032090992 hasConcept C2781048764 @default.
- W2032090992 hasConcept C2781340169 @default.
- W2032090992 hasConcept C37329643 @default.