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- W2032097769 abstract "Abstract Kinetic and thermodynamic activation constants were determined for both directions of heptamolybdate ion (HM)-catalyzed epimerization of two aldopentoses, d -xylose ⇌ d -lyxose. They are related to CD data for [aldose·HM] complexes, and to similar kinetic and thermodynamic data previously reported for two aldohexoses, d -glucose ⇌ d -mannose equilibrium. The results are consistent with Michaelis-Menten type kinetics, and a reveal lower binding affinity for pentoses as compared to hexoses of the same configurational series, raised by the stronger perturbation on binding of the former, and followed by somewhat lower rates of epimerization. A minimal kinetic mechanism is presented, as well as a refined transition-state structure, as compared to that recently reported, involving a d-p interaction between Mo(VI) atoms and the acetalic form of aldose." @default.
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- W2032097769 date "1993-02-01" @default.
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- W2032097769 title "Kinetics and mechanism of the heptamolybdate ion-catalyzed C(2) epimerization of d-xylose and d-lyxose" @default.
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- W2032097769 doi "https://doi.org/10.1016/0304-5102(93)85115-a" @default.
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