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- W2032133208 abstract "Abstract para ‐Substituted with electron donating or electron withdrawing groups triphenyl trithioarsenites, (ArS) 3 As, and octasulfur in refluxing carbon disulfide or chloroform do not give the triaryl tetrathioarsenates, (ArS) 3 As=S, as was claimed in the literature for tris(4‐methylphenyl) tetrathioarsenate. In some cases oxidative decomposition to As 2 O 3 and disulfides ArSSAr was found. When equivalent amounts of the same esters and octasulfur were heated at 105 or 150 °C no As V compound was detected or isolated and again some esters decomposed to As 2 O 3 and disulfides. These experiments demonstrated that the aromatic trithioarsenites do not react with octasulfur, probably because they cannot open the octasulfur ring. These esters in solution react with octasulfur in the presence of a catalytic (10—20 mol%) amount of triethylamine giving disulfides, As 2 O 3 and colored solids which could not be characterized." @default.
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- W2032133208 date "2004-07-01" @default.
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- W2032133208 title "On the Reaction of Triaryl Trithioarsenites, (ArS)3As, with Octasulfur" @default.
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