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• W2032146257 abstract "The chemical reaction involving iodide and nitrite at the surface of platinum disk microelectrodes has been investigated in sulfuric acid medium. Experimental conditions were adjusted to achieve a quasi-first order homogeneous catalytic reaction in quiescent solutions and the kinetic rate constant for this system was found to be 3.2×102 M–1 s–1. Preliminary experiments where electrodes of different radii were used in a wall-jet cell configuration under conditions of variable mass-transfer are presented. The results indicate the advantages of using microelectrodes in this controllable convective system for determining kinetic rate constants of homogeneous chemical reactions coupled to electrode processes." @default.
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• W2032146257 date "1999-04-01" @default.
• W2032146257 modified "2023-09-27" @default.
• W2032146257 title "Studies on the Reaction Between Nitrite and Iodide by Using Microelectrodes in Stationary and Convective Systems" @default.
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• W2032146257 doi "https://doi.org/10.1002/(sici)1521-4109(199904)11:4<234::aid-elan234>3.0.co;2-w" @default.
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