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- W2032169143 abstract "GaAs layers have been grown by metal-organic molecular-beam epitaxy from trimethylgallium and cracked arsenic (${mathrm{As}}_{2}$) on (001)-oriented substrates held at 450 or 500ifmmode^circelsetextdegreefi{}C, and the directions of the (2ifmmodetimeselsetexttimesfi{}4) surface reconstruction observed by high-energy electron diffraction were marked. Postgrowth infrared measurements using polarized light demonstrated that a carbon-hydrogen complex giving vibrational absorption at 2688 ${mathrm{cm}}^{mathrm{ensuremath{-}}1}$ was aligned along the [110] direction, perpendicular to the [1ifmmodebarelsetextasciimacronfi{}10] direction of the surface arsenic dimer bond. After hydrogen passivation in a plasma, this absorption was lost but was regenerated by annealing samples at 450ifmmode^circelsetextdegreefi{}C in a vacuum. The observations confirm a previous assignment of the 2688-${mathrm{cm}}^{mathrm{ensuremath{-}}1}$ defect to a H-(${mathrm{C}}_{mathrm{As}}$${)}_{2}$ complex." @default.
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- W2032169143 title "Orientation relationship of aligned carbon-hydrogen complexes in GaAs formed by the decomposition of trimethylgallium to the directions of the (2×4) surface reconstruction observed during growth" @default.
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- W2032169143 doi "https://doi.org/10.1103/physrevb.50.12250" @default.
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