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- W2032171449 abstract "The reaction of ethylene diamine with Cu(NO3)2� 3H2O and an excess of NaN3 (1:2:4 molar ratio) lead to the formation of copper-azido based polymer [Cu4(N3)8(en)2]n (1), which has been successfully characterized by elemental analyses, IR spectroscopy, single-crystal X-ray diffraction and variable temperature magnetic study. X-ray crystal structure determination of 1 reveals that the structure consists of 1D chains of a centrosymmetric tetranuclear copper(II)-azido cluster, connected through double azido end-to-end bridges. Variable-temperature magnetic studies (between 2 and 300 K) suggest dominant antiferromagnetic interactions in this complex, although ferromagnetic interactions have been observed in all other copper-azido based polymers produced with ethylene diamine reported so far." @default.
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- W2032171449 date "2010-12-01" @default.
- W2032171449 modified "2023-10-02" @default.
- W2032171449 title "Cluster based copper(II)-azide polymer: Synthesis, structure and magnetic study" @default.
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- W2032171449 doi "https://doi.org/10.1016/j.poly.2010.09.012" @default.
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