Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032172364> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2032172364 endingPage "145" @default.
- W2032172364 startingPage "139" @default.
- W2032172364 abstract "Hydrogen atoms from hexamethylethane decomposition have been reacted with perchlo-roethylene in the presence of mesitylene under the high temperature conditions of a single pulse shock tube. Products characteristic of displacement and abstraction reactions have been observed. With the rate expression for methyl displacement from mesitylene by hydrogen atom as an internal standard, k(H+(CH3)3C6H3)→CH3+C6H4(CH3)2)=6.7×1010 exp(−3255/T) 1-mol−1 s−1; over the temperature range 950–1100 K and at pressures near 2.5 atm. k(H+C2Cl4→HCl+C2Cl3)=1.2×1012 exp(−7484/T) 1-mol−1 s−1 and k(H+C2Cl4→Cl+C2HCl3)=1.9×1011 exp(−4589/T) 1-mol−1 s−1 where the uncertainties are estimated to be factors of 1.4 and 1.1 on an absolute and relative basis, respectively. Comparisons are made with results from other olefinic, aromatic and related systems and the effects on hydrogen reactivity with olefins upon chlorine substitution are deduced." @default.
- W2032172364 created "2016-06-24" @default.
- W2032172364 creator A5057707874 @default.
- W2032172364 creator A5075187672 @default.
- W2032172364 date "1991-01-01" @default.
- W2032172364 modified "2023-09-27" @default.
- W2032172364 title "Hydrogen atom attack on perchloroethylene" @default.
- W2032172364 cites W1977672260 @default.
- W2032172364 cites W2011731850 @default.
- W2032172364 cites W2016638977 @default.
- W2032172364 cites W2021883979 @default.
- W2032172364 cites W2021980264 @default.
- W2032172364 cites W2037015583 @default.
- W2032172364 cites W2047868226 @default.
- W2032172364 cites W2052512054 @default.
- W2032172364 cites W2052872009 @default.
- W2032172364 cites W2054914927 @default.
- W2032172364 cites W2056161322 @default.
- W2032172364 cites W2056467995 @default.
- W2032172364 cites W2087284460 @default.
- W2032172364 doi "https://doi.org/10.1016/s0082-0784(06)80252-3" @default.
- W2032172364 hasPublicationYear "1991" @default.
- W2032172364 type Work @default.
- W2032172364 sameAs 2032172364 @default.
- W2032172364 citedByCount "1" @default.
- W2032172364 crossrefType "journal-article" @default.
- W2032172364 hasAuthorship W2032172364A5057707874 @default.
- W2032172364 hasAuthorship W2032172364A5075187672 @default.
- W2032172364 hasConcept C113196181 @default.
- W2032172364 hasConcept C121332964 @default.
- W2032172364 hasConcept C124681953 @default.
- W2032172364 hasConcept C142724271 @default.
- W2032172364 hasConcept C147789679 @default.
- W2032172364 hasConcept C155647269 @default.
- W2032172364 hasConcept C161790260 @default.
- W2032172364 hasConcept C178790620 @default.
- W2032172364 hasConcept C185592680 @default.
- W2032172364 hasConcept C204787440 @default.
- W2032172364 hasConcept C2776640939 @default.
- W2032172364 hasConcept C2776910235 @default.
- W2032172364 hasConcept C2777352791 @default.
- W2032172364 hasConcept C2780263894 @default.
- W2032172364 hasConcept C2993530813 @default.
- W2032172364 hasConcept C39353612 @default.
- W2032172364 hasConcept C505241676 @default.
- W2032172364 hasConcept C512968161 @default.
- W2032172364 hasConcept C71924100 @default.
- W2032172364 hasConcept C81022585 @default.
- W2032172364 hasConcept C97355855 @default.
- W2032172364 hasConceptScore W2032172364C113196181 @default.
- W2032172364 hasConceptScore W2032172364C121332964 @default.
- W2032172364 hasConceptScore W2032172364C124681953 @default.
- W2032172364 hasConceptScore W2032172364C142724271 @default.
- W2032172364 hasConceptScore W2032172364C147789679 @default.
- W2032172364 hasConceptScore W2032172364C155647269 @default.
- W2032172364 hasConceptScore W2032172364C161790260 @default.
- W2032172364 hasConceptScore W2032172364C178790620 @default.
- W2032172364 hasConceptScore W2032172364C185592680 @default.
- W2032172364 hasConceptScore W2032172364C204787440 @default.
- W2032172364 hasConceptScore W2032172364C2776640939 @default.
- W2032172364 hasConceptScore W2032172364C2776910235 @default.
- W2032172364 hasConceptScore W2032172364C2777352791 @default.
- W2032172364 hasConceptScore W2032172364C2780263894 @default.
- W2032172364 hasConceptScore W2032172364C2993530813 @default.
- W2032172364 hasConceptScore W2032172364C39353612 @default.
- W2032172364 hasConceptScore W2032172364C505241676 @default.
- W2032172364 hasConceptScore W2032172364C512968161 @default.
- W2032172364 hasConceptScore W2032172364C71924100 @default.
- W2032172364 hasConceptScore W2032172364C81022585 @default.
- W2032172364 hasConceptScore W2032172364C97355855 @default.
- W2032172364 hasIssue "1" @default.
- W2032172364 hasLocation W20321723641 @default.
- W2032172364 hasOpenAccess W2032172364 @default.
- W2032172364 hasPrimaryLocation W20321723641 @default.
- W2032172364 hasRelatedWork W1987075744 @default.
- W2032172364 hasRelatedWork W1988078639 @default.
- W2032172364 hasRelatedWork W2005354890 @default.
- W2032172364 hasRelatedWork W2013971629 @default.
- W2032172364 hasRelatedWork W2029303291 @default.
- W2032172364 hasRelatedWork W2077478702 @default.
- W2032172364 hasRelatedWork W2083414831 @default.
- W2032172364 hasRelatedWork W2088677220 @default.
- W2032172364 hasRelatedWork W94837907 @default.
- W2032172364 hasRelatedWork W1968027285 @default.
- W2032172364 hasVolume "23" @default.
- W2032172364 isParatext "false" @default.
- W2032172364 isRetracted "false" @default.
- W2032172364 magId "2032172364" @default.
- W2032172364 workType "article" @default.