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- W2032173089 abstract "Complex Os(η5-C5H5)(C⋮CPh){[η2-CH2C(CH3)]PiPr2} (1) reacts with HBF4·OEt2 to give the π-alkyne derivative [Os(η5-C5H5)(η2-HC⋮CPh){[η2-CH2C(CH3)]PiPr2}]BF4 (2), which is transformed to [Os(η5-C5H5)(1,2-dihydro-2-methylnaphth-2-yldiisopropylphosphine)]BF4 (3) as a result of the coupling of the alkyne with the isopropenyl substituent of the starting phosphine. The tridentate coordination mode of the dihydronaphthylphosphine in 3 is proved by X-ray diffraction analysis." @default.
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- W2032173089 date "2005-09-13" @default.
- W2032173089 modified "2023-10-03" @default.
- W2032173089 title "The Cyclopentadienyl-Osmium Moiety as Template for the Formation of a Dihydronaphthylphosphine by Coupling between Phenylacetylene and an α-Alkenylphosphine" @default.
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- W2032173089 doi "https://doi.org/10.1021/om050487q" @default.
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