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- W2032175329 abstract "Some primary processes associated with exciplex systems have been investigated by means of picosecond laser photolysis method, (a) The formation process of the intramolecular charge transfer state of (CH3)2N-C6H4 (CH2) -(1-pyrenyl)(Pn , n = 2, 3) in the excited state depends upon the number of -CH2- group as well as the solvent polarity. The formation process becomes faster with increase of the solvent polarity. It has been demonstrated directly that photo-induced charge transfer brings forth at first a heteroexcimer with loose structure which is followed by the structural change to the one of sandwich type in the case of P3 in 2-propanol. (b) Intermediate exciplex in the photochemical hydrogen abstraction reaction was directly observed for pyrene-N-ethylaniline-hexane ystem. It has been demonstrated that pyrene triplets are produced from pyrene-N-ethylaniline exciplex in hexane within a few nsec, which is much faster than ISC of pyrene-diethylaniline and anthracene-diethylaniline exciplexes." @default.
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- W2032175329 date "1978-01-01" @default.
- W2032175329 modified "2023-10-16" @default.
- W2032175329 title "Picosecond chemistry of some exciplex systems" @default.
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- W2032175329 doi "https://doi.org/10.1016/0022-2860(78)87185-3" @default.
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