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- W2032200142 abstract "Die Titelverbindungen 3 und 7 wurden dargestellt, da in ihnen die semicyclische Doppelbindung wegen einer bicyclofulvenartigen Wechselwirkung der drei π-Systeme polarisiert sein kann. Um eine derartige Polarität zu bestimmen, wurden zum Vergleich eine Reihe von Methylenbicyclo[2.2.1]heptan- und Methylenbicyclo[4.2.1]nonan-Derivaten mit abnehmender Zahl von Doppelbindungen dargestellt. Bicyclofulvenes, I. Synthesis of Methylenebucyclo[2.2.1]heptadiene and Methylenebicyclo[4.2.1]nonatriene The title compounds 3 and 7 have been synthesized because their semicyclic double bond could be polarized by a bicyclofulvene type interaction of the three π-systems. In order to detect such polarization a series of methylenebicyclo[2.2.1]heptane and methylenebicyclo-[4.2.1]nonane derivatives of lesser unsaturation have been prepared for comparison." @default.
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- W2032200142 date "1975-01-01" @default.
- W2032200142 modified "2023-10-17" @default.
- W2032200142 title "Bicyclofulvene, I. Darstellung von Methylenbicyclo[2.2.1]heptadien und Methylenbicyclo[4.2.1]nonatrien" @default.
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- W2032200142 doi "https://doi.org/10.1002/cber.19751080114" @default.
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