Matches in SemOpenAlex for { <https://semopenalex.org/work/W2032206089> ?p ?o ?g. }
- W2032206089 endingPage "9832" @default.
- W2032206089 startingPage "9823" @default.
- W2032206089 abstract "The synthesis and photophysical characterization of two sets of zinc porphyrin platinum acetylide complexes are reported. The two sets of molecules differ in the way the bridging phenyl-ethynyl unit is attached to the porphyrin ring. One set is attached via an ethynyl unit on the β position, while the other set is attached via a phenyl unit on the meso position of the porphyrin. These were compared with previously studied complexes where attachment was made via an ethynyl unit on the meso position. Femtosecond transient absorption measurements showed in all systems a rapid quenching of the porphyrin singlet state. Electron transfer is suggested as the quenching mechanism, followed by an even faster recombination to form both the porphyrin ground and triplet excited states. This is supported by the variation in quenching rate and porphyrin triplet yield with solvent polarity, and the observation of an intermediate state in the meso-phenyl linked systems. The different linking motifs between the dyads resulted in significant variations in electron transfer rates." @default.
- W2032206089 created "2016-06-24" @default.
- W2032206089 creator A5005781048 @default.
- W2032206089 creator A5009130617 @default.
- W2032206089 creator A5010016227 @default.
- W2032206089 creator A5029372142 @default.
- W2032206089 creator A5051797024 @default.
- W2032206089 creator A5052221113 @default.
- W2032206089 creator A5067667577 @default.
- W2032206089 creator A5086184094 @default.
- W2032206089 date "2010-10-04" @default.
- W2032206089 modified "2023-10-13" @default.
- W2032206089 title "Photoinduced Electron Transfer in Zn(II)porphyrin−Bridge−Pt(II)acetylide Complexes: Variation in Rate with Anchoring Group and Position of the Bridge" @default.
- W2032206089 cites W1630368370 @default.
- W2032206089 cites W1964364510 @default.
- W2032206089 cites W1966469469 @default.
- W2032206089 cites W1966624508 @default.
- W2032206089 cites W1969366064 @default.
- W2032206089 cites W1970453628 @default.
- W2032206089 cites W1971944253 @default.
- W2032206089 cites W1975588972 @default.
- W2032206089 cites W1976552014 @default.
- W2032206089 cites W1978432385 @default.
- W2032206089 cites W1978461472 @default.
- W2032206089 cites W1978592868 @default.
- W2032206089 cites W1980216394 @default.
- W2032206089 cites W1981375882 @default.
- W2032206089 cites W1982298817 @default.
- W2032206089 cites W1984967704 @default.
- W2032206089 cites W1986503526 @default.
- W2032206089 cites W1987005502 @default.
- W2032206089 cites W1988875463 @default.
- W2032206089 cites W1991737623 @default.
- W2032206089 cites W1991773387 @default.
- W2032206089 cites W1994392595 @default.
- W2032206089 cites W1997366729 @default.
- W2032206089 cites W1999439343 @default.
- W2032206089 cites W2000034929 @default.
- W2032206089 cites W2001993329 @default.
- W2032206089 cites W2005020545 @default.
- W2032206089 cites W2005095799 @default.
- W2032206089 cites W2008245445 @default.
- W2032206089 cites W2008631597 @default.
- W2032206089 cites W2009559109 @default.
- W2032206089 cites W2013440762 @default.
- W2032206089 cites W2017220615 @default.
- W2032206089 cites W2019274644 @default.
- W2032206089 cites W2027270607 @default.
- W2032206089 cites W2031904472 @default.
- W2032206089 cites W2034786741 @default.
- W2032206089 cites W2035579953 @default.
- W2032206089 cites W2036518565 @default.
- W2032206089 cites W2037413903 @default.
- W2032206089 cites W2046964773 @default.
- W2032206089 cites W2047954651 @default.
- W2032206089 cites W2049745418 @default.
- W2032206089 cites W2059748357 @default.
- W2032206089 cites W2068292733 @default.
- W2032206089 cites W2069506896 @default.
- W2032206089 cites W2070423049 @default.
- W2032206089 cites W2070890578 @default.
- W2032206089 cites W2074054729 @default.
- W2032206089 cites W2075511300 @default.
- W2032206089 cites W2075880879 @default.
- W2032206089 cites W2082782310 @default.
- W2032206089 cites W2089744803 @default.
- W2032206089 cites W2092443097 @default.
- W2032206089 cites W2132635477 @default.
- W2032206089 cites W2141914265 @default.
- W2032206089 cites W2145773666 @default.
- W2032206089 cites W2149275556 @default.
- W2032206089 cites W2153725699 @default.
- W2032206089 cites W2168382386 @default.
- W2032206089 cites W2170549062 @default.
- W2032206089 cites W2170909829 @default.
- W2032206089 cites W2330290939 @default.
- W2032206089 cites W2331378292 @default.
- W2032206089 cites W4213245659 @default.
- W2032206089 cites W4241840676 @default.
- W2032206089 cites W4254640185 @default.
- W2032206089 cites W636144156 @default.
- W2032206089 doi "https://doi.org/10.1021/ic100605t" @default.
- W2032206089 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20919727" @default.
- W2032206089 hasPublicationYear "2010" @default.
- W2032206089 type Work @default.
- W2032206089 sameAs 2032206089 @default.
- W2032206089 citedByCount "20" @default.
- W2032206089 countsByYear W20322060892012 @default.
- W2032206089 countsByYear W20322060892013 @default.
- W2032206089 countsByYear W20322060892014 @default.
- W2032206089 countsByYear W20322060892015 @default.
- W2032206089 countsByYear W20322060892016 @default.
- W2032206089 countsByYear W20322060892019 @default.
- W2032206089 countsByYear W20322060892020 @default.
- W2032206089 countsByYear W20322060892021 @default.
- W2032206089 crossrefType "journal-article" @default.
- W2032206089 hasAuthorship W2032206089A5005781048 @default.
- W2032206089 hasAuthorship W2032206089A5009130617 @default.