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- W2032208957 abstract "Four synthetic routes to poly(L-lactide) with thiol end groups based on ring-opening polymerization of L-lactide (LA) catalysed with tin(II) 2-ethylhexanoate (Sn(Oct) 2 ) are reported. The following alcohols were used as co-initiators of polymerization: 2-sulfanylethan-1-ol, 2-[(2,4-dinitrophenyl)sulfanyl]ethan-1-ol, 2-(tritylsulfanyl)ethan-1-ol and allyl alcohol. End groups introduced into polymers by co-initiators were transformed to thiol groups by a subsequent modification reaction. The efficiencies of the used synthetic methods were evaluated and discussed. The best results were obtained with co-initiator 2-(tritylsulfanyl)ethan-1-ol." @default.
- W2032208957 created "2016-06-24" @default.
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- W2032208957 date "2003-01-01" @default.
- W2032208957 modified "2023-10-17" @default.
- W2032208957 title "Synthesis of Polylactide with Thiol End Groups" @default.
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- W2032208957 doi "https://doi.org/10.1135/cccc20031131" @default.
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