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- W2032267960 abstract "Abstract Evidence was found for the existence in Lavandula officinalis Chaix of 2-glucosyloxy-4-methoxy- cis -cinnamic acid 1 , which yields 7-methoxy showed that D -glucose, L -phenylalanine, and cinnamic acid are common precursors of coumarin and herniarin, but that o - and p -hydroxycinnamic acids are selectively converted to coumarin and herniarin, respectively. Data obtained were consistent with the occurrence of herniarin biosynthesis according to the partial sequence: Cinnamic acid→ p -coumaric acid→ p -methoxycinnamic acid→2-glucosyloxy-4-methoxy- trans -cinnamic acid→-2-glucosyloxy-4-methoxy- cis -cinnamic acid. Umbellic acid (2,4-dihydroxy- trans -cinnamic acid) and umbelliferone were utilized to a minor degree. An improved preparation of umbelliferone-2- 14 C, and syntheses of umbellic acid-carboxy- 14 C, p -methoxycinnamic acid-α- 14 C, 1 and 2-glucosyloxy-4-methoxy- trans -cinnamic acid-α- 14 C are described." @default.
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- W2032267960 date "1963-06-01" @default.
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- W2032267960 title "Biosynthesis of the coumarins IV. The formation of coumarin and herniarin in lavender" @default.
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- W2032267960 doi "https://doi.org/10.1016/s0031-9422(00)82973-8" @default.
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