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• W2032289850 endingPage "415" @default.
• W2032289850 startingPage "410" @default.
• W2032289850 abstract "Reactions of alkenols with cis-Pt(Cl)2(TPPTS)2 (TPPTS = P(m-C6H4SO3Na)3) in water result in [Pt(η3-allyl)(TPPTS)2]+ as the exclusive platinum product with 1 equiv of oxidized alkenol. The η3-allyl is not fluxional in water, and the syn and anti isomers can be distinguished at room temperature. For 3-buten-1-ol and 4-penten-1-ol, in addition to the η3-allyl complex and oxidation of the alkene, catalytic isomerization of the alkene is observed. No reaction occurs for cis-Pt(Cl)2(P(p-tolyl)3)2, cis-Pt(Cl)(THF)(P(p-tolyl)3)2+, or cis-Pt(THF)2(P(p-tolyl)3)22+ with the alkenols in THF, indicating the importance of H2O. Excess Cl- inhibits the reaction. The oxidation product is selectively deuterated. These observations are combined into a proposed mechanism." @default.
• W2032289850 created "2016-06-24" @default.
• W2032289850 creator A5025450074 @default.
• W2032289850 creator A5043742310 @default.
• W2032289850 creator A5073600983 @default.
• W2032289850 date "2005-12-16" @default.
• W2032289850 modified "2023-09-24" @default.
• W2032289850 title "Formation of [Pt(η³-allyl)(TPPTS)₂]⁺ from Reaction of <i>cis</i>-Pt(Cl)₂(TPPTS)₂ with Alkenols in Water" @default.
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• W2032289850 doi "https://doi.org/10.1021/om050540a" @default.
• W2032289850 hasPublicationYear "2005" @default.
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