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- W2032330906 endingPage "487" @default.
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- W2032330906 abstract "The first diastereoselective total synthesis of 5-substituted morpholine-3-phosphonic acids is reported. The principal feature of the synthesis is the introduction of a dimethyl phosphonate group into 5-substituted morpholin-3-ones. The procedure is based on the preparation of N-Boc-(S)-5-phenyl- and N-Boc-(S)-5-benzylmorpholin-3-one from l-phenylglycine and l-phenylalanine methyl esters, followed by the formation of the 3-methoxylated compounds and subsequent reaction with trimethyl phosphite in the presence of BF3·OEt2. Diastereoselectivity in the formation of cis-disubstituted products is in agreement with the nucleophilic addition to other methoxylated derivatives." @default.
- W2032330906 created "2016-06-24" @default.
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- W2032330906 date "2014-04-01" @default.
- W2032330906 modified "2023-09-27" @default.
- W2032330906 title "Diastereoselective synthesis of novel 5-substituted morpholine-3-phosphonic acids: further exploitation of N-acyliminium intermediates" @default.
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- W2032330906 doi "https://doi.org/10.1016/j.tetasy.2014.02.014" @default.
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